Electro-and solar-driven fuel synthesis with first row transition metal complexes

KE Dalle, J Warnan, JJ Leung, B Reuillard… - Chemical …, 2019 - ACS Publications
The synthesis of renewable fuels from abundant water or the greenhouse gas CO2 is a
major step toward creating sustainable and scalable energy storage technologies. In the last …

Transition Metal Complexes as Catalysts for the Electroconversion of CO2: An Organometallic Perspective

NW Kinzel, C Werlé, W Leitner - … Chemie International Edition, 2021 - Wiley Online Library
The electrocatalytic transformation of carbon dioxide has been a topic of interest in the field
of CO2 utilization for a long time. Recently, the area has seen increasing dynamics as an …

Mechanistic aspects of CO2 reduction catalysis with manganese-based molecular catalysts

DC Grills, MZ Ertem, M McKinnon, KT Ngo… - Coordination Chemistry …, 2018 - Elsevier
One approach for the conversion of CO 2 into fuels or fuel precursors is the proton-coupled
reduction of CO 2 to CO or formic acid, using transition metal complexes as catalysts in …

Mechanically Constrained Catalytic Mn(CO)3Br Single Sites in a Two-Dimensional Covalent Organic Framework for CO2 Electroreduction in H2O

GC Dubed Bandomo, SS Mondal, F Franco… - ACS …, 2021 - ACS Publications
The development of CO2 electroreduction (CO2RR) catalysts based on covalent organic
frameworks (COFs) is an emerging strategy to produce synthetic fuels. However, our …

Manganese Carbonyl Complexes as Selective Electrocatalysts for CO2 Reduction in Water and Organic Solvents

B Siritanaratkul, C Eagle, AJ Cowan - Accounts of Chemical …, 2022 - ACS Publications
Conspectus The electrochemical reduction of CO2 provides a way to sustainably generate
carbon-based fuels and feedstocks. Molecular CO2 reduction electrocatalysts provide …

Highly Selective and Durable Photochemical CO2 Reduction by Molecular Mn(I) Catalyst Fixed on a Particular Dye-Sensitized TiO2 Platform

SJ Woo, S Choi, SY Kim, PS Kim, JH Jo, CH Kim… - ACS …, 2019 - ACS Publications
A Mn (I)-based hybrid system (OrgD-| TiO2|-MnP) for photocatalytic CO2 reduction is
designed to be a coassembly of Mn (4, 4′-Y2-bpy)(CO) 3Br (MnP; Y= CH2PO (OH) 2) and …

Photocatalytic Reduction of CO2 to CO in Aqueous Solution under Red-Light Irradiation by a Zn-Porphyrin-Sensitized Mn(I) Catalyst

J Shipp, S Parker, S Spall, SL Peralta-Arriaga… - Inorganic …, 2022 - ACS Publications
This work demonstrates photocatalytic CO2 reduction by a noble-metal-free photosensitizer-
catalyst system in aqueous solution under red-light irradiation. A water-soluble Mn (I) …

Electrochemical CO2 reduction with earth-abundant metal catalysts

L Rotundo, R Gobetto, C Nervi - Current Opinion in Green and Sustainable …, 2021 - Elsevier
Energy production and CO 2 emissions are strictly connected. One of the most efficient and
straightforward mitigations to the climate change is the conversion of CO 2 into chemicals …

Cobalt porphyrin immobilized on the TiO2 nanotube electrode for CO2 electroreduction in aqueous solution

S Gu, AN Marianov, Y Zhu, Y Jiang - Journal of Energy Chemistry, 2021 - Elsevier
Herein we report CO 2 electrochemical reduction reaction (CO 2 ERR) on the cobalt
tetraphenylporphyrin (CoTPP) modified TiO 2 nanotube (TNT) electrode. It was found the …

Toward the Understanding of the Structure–Activity Correlation in Single-Site Mn Covalent Organic Frameworks for Electrocatalytic CO2 Reduction

GC Dubed Bandomo, F Franco, C Liu… - ACS Applied Energy …, 2024 - ACS Publications
The encapsulation of organometallic complexes into reticular covalent organic frameworks
(COFs) represents an effective strategy for the immobilization of molecular electrocatalysts …