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Quantum mechanical studies on the photophysics and the photochemistry of nucleic acids and nucleobases
The photophysics and photochemistry of DNA is of great importance due to the potential
damage of the genetic code by UV light. Quantum mechanical studies have played a key …
damage of the genetic code by UV light. Quantum mechanical studies have played a key …
Mechanisms for DNA charge transport
JC Genereux, JK Barton - Chemical reviews, 2010 - ACS Publications
DNA charge transport (CT) chemistry has received considerable attention by scientific
researchers over the past 15 years since our first provocative publication on long-range CT …
researchers over the past 15 years since our first provocative publication on long-range CT …
Analysis of excitonic and charge transfer interactions from quantum chemical calculations
A procedure for a detailed analysis of excited states in systems of interacting chromophores
is proposed. By considering the one-electron transition density matrix, a wealth of …
is proposed. By considering the one-electron transition density matrix, a wealth of …
DNA excited-state dynamics: from single bases to the double helix
Ultraviolet light is strongly absorbed by DNA, producing excited electronic states that
sometimes initiate damaging photochemical reactions. Fully map** the reactive and …
sometimes initiate damaging photochemical reactions. Fully map** the reactive and …
Excited state dynamics of DNA bases
K Kleinermanns, D Nachtigallová… - International Reviews in …, 2013 - Taylor & Francis
Biochemical reactions are subject to the particular environmental conditions of planet earth,
including solar irradiation. How DNA responds to radiation is relevant to human health …
including solar irradiation. How DNA responds to radiation is relevant to human health …
[HTML][HTML] Are the five natural DNA/RNA base monomers a good choice from natural selection?: A photochemical perspective
L Serrano-Andres, M Merchan - Journal of Photochemistry and …, 2009 - Elsevier
In order to prevent the damaging effects of sun radiation in the genetic material, its
constituent chromophores, the five natural DNA/RNA nucleobases cytosine, thymine, uracil …
constituent chromophores, the five natural DNA/RNA nucleobases cytosine, thymine, uracil …
Quantum chemical modeling of the photoinduced activity of multichromophoric biosystems: focus review
Multichromophoric biosystems represent a broad family with very diverse members, ranging
from light-harvesting pigment–protein complexes to nucleic acids. The former are designed …
from light-harvesting pigment–protein complexes to nucleic acids. The former are designed …
A doorway state leads to photostability or triplet photodamage in thymine DNA
WM Kwok, C Ma, DL Phillips - Journal of the American Chemical …, 2008 - ACS Publications
Ultraviolet irradiation of DNA produces electronic excited states that predominantly eliminate
the excitation energy by returning to the ground state (photostability) or following minor …
the excitation energy by returning to the ground state (photostability) or following minor …
Electronic excited states responsible for dimer formation upon UV absorption directly by thymine strands: joint experimental and theoretical study
The study addresses interconnected issues related to two major types of cycloadditions
between adjacent thymines in DNA leading to cyclobutane dimers (T<> Ts) and (6-4) …
between adjacent thymines in DNA leading to cyclobutane dimers (T<> Ts) and (6-4) …
UV excitation of single DNA and RNA strands produces high yields of exciplex states between two stacked bases
T Takaya, C Su, K de La Harpe… - Proceedings of the …, 2008 - pnas.org
Excited electronic states created by UV excitation of the diribonucleoside monophosphates
ApA, ApG, ApC, ApU, and CpG were studied by the femtosecond transient-absorption …
ApA, ApG, ApC, ApU, and CpG were studied by the femtosecond transient-absorption …