Design and applications of water-soluble coordination cages
Compartmentalization of the aqueous space within a cell is necessary for life. In similar
fashion to the nanometer-scale compartments in living systems, synthetic water-soluble …
fashion to the nanometer-scale compartments in living systems, synthetic water-soluble …
Metal–organic cages for molecular separations
Separation technology is central to industries as diverse as petroleum, pharmaceuticals,
mining and life sciences. Metal–organic cages, a class of molecular containers formed via …
mining and life sciences. Metal–organic cages, a class of molecular containers formed via …
Molecular recognition in water using macrocyclic synthetic receptors
Molecular recognition in water using macrocyclic synthetic receptors constitutes a vibrant
and timely research area of supramolecular chemistry. Pioneering examples on the topic …
and timely research area of supramolecular chemistry. Pioneering examples on the topic …
Functional capsules via subcomponent self-assembly
Conspectus Coordination-driven self-assembly can produce large, symmetrical, hollow
cages that are synthetically easy to access. The functions provided by these aesthetically …
cages that are synthetically easy to access. The functions provided by these aesthetically …
Permanently microporous metal–organic polyhedra
AJ Gosselin, CA Rowland, ED Bloch - Chemical reviews, 2020 - ACS Publications
As compared to porous network solids, including metal–organic frameworks, covalent–
organic frameworks, porous aromatic frameworks, and zeolites, porous molecular materials …
organic frameworks, porous aromatic frameworks, and zeolites, porous molecular materials …
Self‐Assembly of Highly Stable Zirconium (IV) Coordination Cages with Aggregation Induced Emission Molecular Rotors for Live‐Cell Imaging
The self‐assembly of highly stable zirconium (IV)‐based coordination cages with
aggregation induced emission (AIE) molecular rotors for in vitro bio‐imaging is reported. The …
aggregation induced emission (AIE) molecular rotors for in vitro bio‐imaging is reported. The …
Dynamic Metallosupramolecular Cages Containing 12 Adaptable Pockets for High-Order Guest Binding Beyond Biomimicry
YH Huang, YL Lu, J Ruan, SP Zheng… - Journal of the …, 2023 - ACS Publications
Molecular recognition lies at the heart of biological functions, which inspires lasting research
in artificial host syntheses to mimic biomolecules that can recognize, process, and transport …
in artificial host syntheses to mimic biomolecules that can recognize, process, and transport …
Beyond platonic: how to build metal–organic polyhedra capable of binding low-symmetry, information-rich molecular cargoes
The field of metallosupramolecular chemistry has advanced rapidly in recent years. Much
work in this area has focused on the formation of hollow self-assembled metal-organic …
work in this area has focused on the formation of hollow self-assembled metal-organic …
Reversible chromism of spiropyran in the cavity of a flexible coordination cage
Confining molecules to volumes only slightly larger than the molecules themselves can
profoundly alter their properties. Molecular switches—entities that can be toggled between …
profoundly alter their properties. Molecular switches—entities that can be toggled between …
Anionic Templates Drive Conversion between a ZnII9L6 Tricapped Trigonal Prism and ZnII6L4 Pseudo-Octahedra
HK Liu, TK Ronson, K Wu, D Luo… - Journal of the American …, 2023 - ACS Publications
This work introduces the use of 8-aminoquinoline subcomponents to generate complex
three-dimensional structures. Together with a tris (formylpyridine), 8-aminoquinoline …
three-dimensional structures. Together with a tris (formylpyridine), 8-aminoquinoline …