Design and applications of water-soluble coordination cages

EG Percástegui, TK Ronson, JR Nitschke - Chemical Reviews, 2020 - ACS Publications
Compartmentalization of the aqueous space within a cell is necessary for life. In similar
fashion to the nanometer-scale compartments in living systems, synthetic water-soluble …

Metal–organic cages for molecular separations

D Zhang, TK Ronson, YQ Zou, JR Nitschke - Nature Reviews Chemistry, 2021 - nature.com
Separation technology is central to industries as diverse as petroleum, pharmaceuticals,
mining and life sciences. Metal–organic cages, a class of molecular containers formed via …

Molecular recognition in water using macrocyclic synthetic receptors

L Escobar, P Ballester - Chemical Reviews, 2021 - ACS Publications
Molecular recognition in water using macrocyclic synthetic receptors constitutes a vibrant
and timely research area of supramolecular chemistry. Pioneering examples on the topic …

Functional capsules via subcomponent self-assembly

D Zhang, TK Ronson, JR Nitschke - Accounts of chemical …, 2018 - ACS Publications
Conspectus Coordination-driven self-assembly can produce large, symmetrical, hollow
cages that are synthetically easy to access. The functions provided by these aesthetically …

Permanently microporous metal–organic polyhedra

AJ Gosselin, CA Rowland, ED Bloch - Chemical reviews, 2020 - ACS Publications
As compared to porous network solids, including metal–organic frameworks, covalent–
organic frameworks, porous aromatic frameworks, and zeolites, porous molecular materials …

Self‐Assembly of Highly Stable Zirconium (IV) Coordination Cages with Aggregation Induced Emission Molecular Rotors for Live‐Cell Imaging

J Dong, Y Pan, H Wang, K Yang, L Liu… - Angewandte Chemie …, 2020 - Wiley Online Library
The self‐assembly of highly stable zirconium (IV)‐based coordination cages with
aggregation induced emission (AIE) molecular rotors for in vitro bio‐imaging is reported. The …

Dynamic Metallosupramolecular Cages Containing 12 Adaptable Pockets for High-Order Guest Binding Beyond Biomimicry

YH Huang, YL Lu, J Ruan, SP Zheng… - Journal of the …, 2023 - ACS Publications
Molecular recognition lies at the heart of biological functions, which inspires lasting research
in artificial host syntheses to mimic biomolecules that can recognize, process, and transport …

Beyond platonic: how to build metal–organic polyhedra capable of binding low-symmetry, information-rich molecular cargoes

CT McTernan, JA Davies, JR Nitschke - Chemical Reviews, 2022 - ACS Publications
The field of metallosupramolecular chemistry has advanced rapidly in recent years. Much
work in this area has focused on the formation of hollow self-assembled metal-organic …

Reversible chromism of spiropyran in the cavity of a flexible coordination cage

D Samanta, D Galaktionova, J Gemen… - Nature …, 2018 - nature.com
Confining molecules to volumes only slightly larger than the molecules themselves can
profoundly alter their properties. Molecular switches—entities that can be toggled between …

Anionic Templates Drive Conversion between a ZnII9L6 Tricapped Trigonal Prism and ZnII6L4 Pseudo-Octahedra

HK Liu, TK Ronson, K Wu, D Luo… - Journal of the American …, 2023 - ACS Publications
This work introduces the use of 8-aminoquinoline subcomponents to generate complex
three-dimensional structures. Together with a tris (formylpyridine), 8-aminoquinoline …