Understanding MOF flexibility: An analysis focused on pillared layer MOFs as a model system

I Senkovska, V Bon, L Abylgazina, M Mendt… - Angewandte …, 2023 - Wiley Online Library
Flexible porous frameworks are at the forefront of materials research. A unique feature is
their ability to open and close their pores in an adaptive manner induced by chemical and …

Inorganic–organic hybrid dielectrics for energy conversion: mechanism, strategy, and applications

F Wu, A **e, L Jiang, S Mukherjee… - Advanced Functional …, 2023 - Wiley Online Library
Dielectric materials with higher energy storage and electromagnetic (EM) energy conversion
are in high demand to advance electronic devices, military stealth, and mitigate EM wave …

Simulations in the era of exascale computing

C Chang, VL Deringer, KS Katti… - Nature Reviews …, 2023 - nature.com
Exascale computers—supercomputers that can perform 1018 floating point operations per
second—started coming online in 2022: in the United States, Frontier launched as the first …

[HTML][HTML] Machine learning potentials for metal-organic frameworks using an incremental learning approach

S Vandenhaute, M Cools-Ceuppens… - npj Computational …, 2023 - nature.com
Computational modeling of physical processes in metal-organic frameworks (MOFs) is
highly challenging due to the presence of spatial heterogeneities and complex operating …

Recent progress on MOF/MXene nanoarchitectures: A new era in coordination chemistry for energy storage and conversion

S Venkateswarlu, S Vallem, M Umer, NVV Jyothi… - Journal of Energy …, 2023 - Elsevier
The development of urbanization and industrialization leads to rapid depletion of fossil fuels.
Therefore, the production of fuel from renewable resources is highly desired …

Operando modeling of zeolite-catalyzed reactions using first-principles molecular dynamics simulations

V Van Speybroeck, M Bocus, P Cnudde… - ACS …, 2023 - ACS Publications
Within this Perspective, we critically reflect on the role of first-principles molecular dynamics
(MD) simulations in unraveling the catalytic function within zeolites under operating …

The role of dynamic metal-ligand bonds in metal-organic framework chemistry

JL Obeso, MT Huxley, C Leyva, JG Flores… - Coordination Chemistry …, 2023 - Elsevier
Metal-organic frameworks (MOFs) are an emerging class of porous materials composed of
metal ions or clusters interconnected by organic ligands. Many proposed applications for …

Functional dynamics in framework materials

S Krause, JV Milić - Communications Chemistry, 2023 - nature.com
Dynamic crystalline materials have emerged as a unique category of condensed phase
matter that combines crystalline lattice with components that display dynamic behavior in the …

Spatiotemporal Design of the Metal–Organic Framework DUT‐8 (M)

H Miura, V Bon, I Senkovska, S Ehrling… - Advanced …, 2023 - Wiley Online Library
Switchable metal–organic frameworks (MOFs) change their structure in time and selectively
open their pores adsorbing guest molecules, leading to highly selective separation …

MOFs in the time domain

DJ Cerasale, DC Ward, TL Easun - Nature Reviews Chemistry, 2022 - nature.com
Many of the proposed applications of metal–organic framework (MOF) materials may fail to
materialize if the community does not fully address the difficult fundamental work needed to …