Platonic and Archimedean solids in discrete metal-containing clusters
XM Luo, YK Li, XY Dong, SQ Zang - Chemical Society Reviews, 2023 - pubs.rsc.org
Metal-containing clusters have attracted increasing attention over the past 2–3 decades.
This intense interest can be attributed to the fact that these discrete metal aggregates, whose …
This intense interest can be attributed to the fact that these discrete metal aggregates, whose …
Polyoxometalate-assisted synthesis of transition-metal cubane clusters as artificial mimics of the oxygen-evolving center of photosystem II
ZJ Liu, XL Wang, C Qin, ZM Zhang, YG Li… - Coordination chemistry …, 2016 - Elsevier
Abstract The {Mn 4 O 5 Ca} cluster of photosystem II is a well-known cubane-like transition-
metal (TM) cluster that plays important roles in solar energy conversion. The artificial …
metal (TM) cluster that plays important roles in solar energy conversion. The artificial …
Ring-Shaped Polyoxometalate Built by {Mn4PW9} and PO4 Units for Efficient Visible-Light-Driven Hydrogen Evolution
HL Li, M Zhang, C Lian, ZL Lang, H Lv… - CCS …, 2021 - chinesechemsoc.org
A novel mixed-valence, ring-shaped multinuclear Mn-containing polyoxometalate,[H2N
(CH3) 2] 15NaH8-[MnIII3MnIV (μ3-O) 3 (OAc) PO4 (B-α-PW9O34)] 4· 36H2O (1) was made …
(CH3) 2] 15NaH8-[MnIII3MnIV (μ3-O) 3 (OAc) PO4 (B-α-PW9O34)] 4· 36H2O (1) was made …
Special-selective C–H oxidation of toluene to benzaldehyde by a hybrid polyoxometalate photocatalyst including a rare [P6W48Fe6O180] 30–anion
It is a challenge to develop new photocatalysts for high selective oxidation of primary carbon-
hydrogen (C–H) bonds with O 2 under mild condition. Herein, a novel hybrid K 6 (H 2 O) 8 H …
hydrogen (C–H) bonds with O 2 under mild condition. Herein, a novel hybrid K 6 (H 2 O) 8 H …
Investigating the autocatalytically driven formation of Keggin-based polyoxometalate clusters
The term self-assembly is used to describe the formation of many molecules and
supramolecular architectures, but often, the precise mechanism is neglected. Here, we have …
supramolecular architectures, but often, the precise mechanism is neglected. Here, we have …
Two new sandwich-type manganese {Mn5}-substituted polyoxotungstates: Syntheses, crystal structures, electrochemistry, and magnetic properties
Herein we report two pentanuclear MnII-substituted sandwich-type polyoxotungstate
complexes,[{Mn (bpy)} 2Na (H2O) 2 (MnCl) 2 {Mn (H2O)}(AsW9O33) 2] 9–and [{Mn (bpy)} …
complexes,[{Mn (bpy)} 2Na (H2O) 2 (MnCl) 2 {Mn (H2O)}(AsW9O33) 2] 9–and [{Mn (bpy)} …
The main progress over the past decade and future outlook on high-nuclear transition-metal substituted polyoxotungstates: from synthetic strategies, structural features …
X Ma, H Li, L Chen, J Zhao - Dalton Transactions, 2016 - pubs.rsc.org
Currently, transition-metal substituted polyoxotungstates (TMSPTs) have developed as a fast
growing and challengeable subfamily of polyoxoxmetalates (POMs). Before 2005, the …
growing and challengeable subfamily of polyoxoxmetalates (POMs). Before 2005, the …
Assembly of Fe-substituted Dawson-type nanoscale selenotungstate clusters with photocatalytic H 2 evolution activity
WC Chen, C Qin, XL Wang, YG Li, HY Zang… - Chemical …, 2014 - pubs.rsc.org
Two Fe-substituted Dawson-type nanoscale selenotungstate clusters,{Fe6Se6W34} and
{Fe10Se8W62} involving {α-Se2W14} and {γ-Se2W14} building blocks, have been isolated …
{Fe10Se8W62} involving {α-Se2W14} and {γ-Se2W14} building blocks, have been isolated …
Stabilization of Tetravalent 4f (Ce), 5d (Hf), or 5f (Th, U) Clusters by the [α-SiW9O34]10– Polyoxometalate
S Duval, S Beghin, C Falaise, X Trivelli… - Inorganic …, 2015 - ACS Publications
The reaction of Na10 [α-SiW9O34] with tetravalent metallic cations such as 4f ((NH4) 2Ce
(NO3) 6), 5d (HfCl4), or 5f (UCl4 and Th (NO3) 4) in a pH 4.7 sodium acetate buffer solution …
(NO3) 6), 5d (HfCl4), or 5f (UCl4 and Th (NO3) 4) in a pH 4.7 sodium acetate buffer solution …
A huge novel polyoxometalate-based cluster Fe 10 P 4 W 32 exhibiting prominent electrocatalytic activity for the oxygen evolution reaction and third-order NLO …
W Jiang, XM Liu, J Liu, J Shi, JP Cao, XM Luo… - Chemical …, 2019 - pubs.rsc.org
Two novel POM-based huge clusters modified by conjugated organic ligands (DAPSC),{
Fe10P4W32} and {Fe8MoW18}, have been successfully isolated. Compound 1 consists of a …
Fe10P4W32} and {Fe8MoW18}, have been successfully isolated. Compound 1 consists of a …