Atom transfer radical polymerization: a mechanistic perspective

F Lorandi, M Fantin… - Journal of the American …, 2022 - ACS Publications
Since its inception, atom transfer radical polymerization (ATRP) has seen continuous
evolution in terms of the design of the catalyst and reaction conditions; today, it is one of the …

Photoinduced organocatalyzed atom transfer radical polymerization (O-ATRP): precision polymer synthesis using organic photoredox catalysis

DA Corbin, GM Miyake - Chemical reviews, 2021 - ACS Publications
The development of photoinduced organocatalyzed atom transfer radical polymerization (O-
ATRP) has received considerable attention since its introduction in 2014. Expanding on …

Precision polymer synthesis by controlled radical polymerization: Fusing the progress from polymer chemistry and reaction engineering

YN Zhou, JJ Li, TT Wang, YY Wu, ZH Luo - Progress in Polymer Science, 2022 - Elsevier
During the first 100 years of polymer science, controlled radical polymerization (also
recommended as reversible deactivation radical polymerization) is undoubtedly a …

Current status and outlook for ATRP

K Matyjaszewski - European Polymer Journal, 2024 - Elsevier
Atom transfer radical polymerization (ATRP) is one of the most often used controlled radical
polymerization techniques. It employs very small amounts (ppm) of Cu complexes in the …

Electron‐Poor Acridones and Acridiniums as Super Photooxidants in Molecular Photoelectrochemistry by Unusual Mechanisms

J Žurauskas, S Boháčová, S Wu, V Butera… - Angewandte …, 2023 - Wiley Online Library
Electron‐deficient acridones and in situ generated acridinium salts are reported as potent,
closed‐shell photooxidants that undergo surprising mechanisms. When bridging acyclic …

Mechanistic and kinetic studies of visible light photoredox reactions

ED Talbott, NL Burnett, JR Swierk - Chemical Physics Reviews, 2023 - pubs.aip.org
The use of visible light to enable small molecule synthesis has grown substantially over the
last 15 years. While much of the focus has been on the development of new methods …

Long-lived triplet state carbon nitride (urea-CN x) catalyzed metal-free photo-ATRP with oxygen acceleration

C Wang, B Hu, X Guo, L Lei - Green Chemistry, 2024 - pubs.rsc.org
In this study, a long-lived triplet state urea-functionalized carbon nitride (urea-CNx) was
successfully synthesized. It possesses a significant specific surface area, an extended …

Phenanthrene-extended phenazine dication: An electrochromic conformational switch presenting dual reactivity

J Dosso, B Bartolomei, N Demitri… - Journal of the …, 2022 - ACS Publications
The synthesis and isolation of one of the few examples of a π-extended diamagnetic
phenazine dication have been achieved by oxidizing a phenanthrene-based …

Synthetic, biological and optoelectronic properties of phenoxazine and its derivatives: a state of the art review

C Sadhu, AK Mitra - Molecular Diversity, 2024 - Springer
Phenoxazines have sparked a lot of interest owing to their numerous applications in material
science, organic light-emitting diodes, photoredox catalyst, dye-sensitized solar cells and …

Impact of alkyl core substitution kinetics in diaryl dihydrophenazine photoredox catalysts on properties and performance in O-ATRP

KO Puffer, DA Corbin, GM Miyake - ACS catalysis, 2023 - ACS Publications
Organocatalyzed atom transfer radical polymerization (O-ATRP) is a controlled radical
polymerization method mediated by organic photoredox catalysts (PCs) for producing …