Supramolecular coordination cages for artificial photosynthesis and synthetic photocatalysis
Because sunlight is the most abundant energy source on earth, it has huge potential for
practical applications ranging from sustainable energy supply to light driven chemistry. From …
practical applications ranging from sustainable energy supply to light driven chemistry. From …
Molecular cavity for catalysis and formation of metal nanoparticles for use in catalysis
The employment of weak intermolecular interactions in supramolecular chemistry offers an
alternative approach to project artificial chemical environments like the active sites of …
alternative approach to project artificial chemical environments like the active sites of …
Design and applications of water-soluble coordination cages
Compartmentalization of the aqueous space within a cell is necessary for life. In similar
fashion to the nanometer-scale compartments in living systems, synthetic water-soluble …
fashion to the nanometer-scale compartments in living systems, synthetic water-soluble …
Chemical reactivity under nanoconfinement
Confining molecules can fundamentally change their chemical and physical properties.
Confinement effects are considered instrumental at various stages of the origins of life, and …
Confinement effects are considered instrumental at various stages of the origins of life, and …
Molecular barrels as potential hosts: from synthesis to applications
Self-assembled discrete molecular architectures that show selective molecular recognition
within their internal cavities are highly desirable. Such hosts often show guest recognition …
within their internal cavities are highly desirable. Such hosts often show guest recognition …
Picking the lock of coordination cage catalysis
The design principles of metallo-organic assembly reactions have facilitated access to
hundreds of coordination cages of varying size and shape. Many of these assemblies …
hundreds of coordination cages of varying size and shape. Many of these assemblies …
Strategies for binding multiple guests in metal–organic cages
The binding of multiple guests by a single entity can lead to new modes of host–guest
interactions and thus new applications in, for example, catalysis and sensing. With the aim of …
interactions and thus new applications in, for example, catalysis and sensing. With the aim of …
Photochemistry and photophysics of MOFs: steps towards MOF-based sensing enhancements
EA Dolgopolova, AM Rice, CR Martin… - Chemical Society …, 2018 - pubs.rsc.org
In this review, we highlight how recent advances achieved in the fields of photochemistry
and photophysics of metal–organic frameworks (MOFs) could be applied towards the …
and photophysics of metal–organic frameworks (MOFs) could be applied towards the …
Supramolecular catalysis. Part 2: artificial enzyme mimics
The design of artificial catalysts able to compete with the catalytic proficiency of enzymes is
an intense subject of research. Non-covalent interactions are thought to be involved in …
an intense subject of research. Non-covalent interactions are thought to be involved in …
Supramolecular photochemistry as a potential synthetic tool: photocycloaddition
Photochemistry, bearing significant applications in natural and man-made events such as
photosynthesis, vision, photolithography, photodynamic therapy, etc., is yet to become a …
photosynthesis, vision, photolithography, photodynamic therapy, etc., is yet to become a …