Redox-active ligand promoted multielectron reactivity at earth-abundant transition metal complexes
The introduction of redox-active ligands into transition metal complexes can lead to novel
redox behavior due to the ability of these ligands to serve as electron reservoirs. This feature …
redox behavior due to the ability of these ligands to serve as electron reservoirs. This feature …
Photocatalysts for CO2 reduction and computational insights
Global warming is caused by excessive CO 2 production, and reducing CO 2 emissions is a
viable way to counteract this. It has been extensively studied how light-driven processes …
viable way to counteract this. It has been extensively studied how light-driven processes …
Synergistic Porosity and Charge Effects in a Supramolecular Porphyrin Cage Promote Efficient Photocatalytic CO2 Reduction**
We present a supramolecular approach to catalyzing photochemical CO2 reduction through
second‐sphere porosity and charge effects. An iron porphyrin box (PB) bearing 24 cationic …
second‐sphere porosity and charge effects. An iron porphyrin box (PB) bearing 24 cationic …
Charge transfer chromophores derived from 3d-row transition metal complexes
KI Pashanova, IV Ershova, OY Trofimova… - Molecules, 2022 - mdpi.com
A series of new charge transfer (CT) chromophores of “α-diimine-MII-catecholate” type
(where M is 3d-row transition metals—Cu, Ni, Co) were derived from 4, 4′-di-tert-butyl-2 …
(where M is 3d-row transition metals—Cu, Ni, Co) were derived from 4, 4′-di-tert-butyl-2 …
Sensitized and Self-Sensitized Photocatalytic CO2 Reduction to HCO2– and CO under Visible Light with Ni(II) CNC-Pincer Catalysts
Robust earth-abundant transition metal-based photocatalysts are needed for photocatalytic
CO2 reduction. A series of six Ni (II) complexes have been synthesized with a tridentate …
CO2 reduction. A series of six Ni (II) complexes have been synthesized with a tridentate …
Selective and Efficient Light-Driven CO2 Reduction to CO with a Heptacoordinated Polypyridine Iron(II) Catalyst
The selective generation of carbon-based products in the presence of proton donors
currently represents one of the major goals in the catalysis of the CO2 reduction reaction …
currently represents one of the major goals in the catalysis of the CO2 reduction reaction …
Mechanistic Insights into Photochemical CO2 Reduction to CH4 by a Molecular Iron–Porphyrin Catalyst
JY Chen, M Li, RZ Liao - Inorganic Chemistry, 2023 - ACS Publications
Iron tetraphenylporphyrin complex modified with four trimethylammonium groups (Fe-p-
TMA) is found to be capable of catalyzing the eight-electron eight-proton reduction of CO2 to …
TMA) is found to be capable of catalyzing the eight-electron eight-proton reduction of CO2 to …
Bioinspired motifs in proton and CO 2 reduction with 3d-metal polypyridine complexes
The synthesis of active and efficient catalysts for solar fuel generation is nowadays of high
relevance for the scientific community, but at the same time poses great challenges. Critical …
relevance for the scientific community, but at the same time poses great challenges. Critical …
Cobalt Tetracationic 3,4‐Pyridinoporphyrazine for Direct CO2 to Methanol Conversion Esca** the CO Intermediate Pathway
Molecular catalysts offer a unique opportunity to implement different chemical functionalities
to steer the efficiency and selectivity for the CO2 reduction for instance. Metalloporphyrins …
to steer the efficiency and selectivity for the CO2 reduction for instance. Metalloporphyrins …
Ligand-Bound CO2 as a Nonclassical Route toward Efficient Photocatalytic CO2 Reduction with a Ni N-Confused Porphyrin
H Yuan, A Krishna, Z Wei, Y Su, J Chen… - Journal of the …, 2024 - ACS Publications
Implementing the synergistic effects between the metal and the ligand has successfully
streamlined the energetics for CO2 activation and gained high catalytic activities …
streamlined the energetics for CO2 activation and gained high catalytic activities …