Kinetics of atom transfer radical polymerization

P Krys, K Matyjaszewski - European Polymer Journal, 2017 - Elsevier
This review encompasses the fundamentals of kinetics of atom transfer radical
polymerization (ATRP). ATRP is a versatile reversible-deactivation radical polymerization …

Rate coefficients of free-radical polymerization deduced from pulsed laser experiments

S Beuermann, M Buback - Progress in Polymer Science, 2002 - Elsevier
Pulsed laser techniques have enormously improved the quality by which rate coefficients of
individual steps in free-radical polymerization may be measured. Pulsed laser initiated …

The scope for synthesis of macro-RAFT agents by sequential insertion of single monomer units

S Houshyar, DJ Keddie, G Moad, RJ Mulder… - Polymer …, 2012 - pubs.rsc.org
The scope for synthesis of new macro-RAFT agents (Z–C (S) S–(M)–R) by sequential
insertion of monomers (M)'one at a time'into an initial RAFT agent (Z–C (S) S–R) has been …

PLP− SEC study into free-radical propagation rate of nonionized acrylic acid in aqueous solution

I Lacík, S Beuermann, M Buback - Macromolecules, 2003 - ACS Publications
Pulsed laser polymerization (PLP) in conjunction with size-exclusion chromatography
(SEC), both being carried out in the aqueous phase, was used to determine propagation …

Free-radical propagation rate coefficient of nonionized methacrylic acid in aqueous solution from low monomer concentrations to bulk polymerization

S Beuermann, M Buback, P Hesse, I Lacík - Macromolecules, 2006 - ACS Publications
The propagation rate coefficient, kp, for free-radical polymerization of nonionized
methacrylic acid (MAA) in aqueous solution has been studied via pulsed laser …

Critically Evaluated Rate Coefficients for Free‐Radical Polymerization, 4

S Beuermann, M Buback, TP Davis… - Macromolecular …, 2003 - Wiley Online Library
Propagation rate coefficients, kp, which have been previously reported by several groups for
free‐radical bulk polymerizations of cyclohexyl methacrylate (CHMA), glycidyl methacrylate …

Prediction of chain propagation rate constants of polymerization reactions in aqueous NIPAM/BIS and VCL/BIS systems

LC Kröger, WA Kopp, K Leonhard - The Journal of Physical …, 2017 - ACS Publications
Microgels have a wide range of possible applications and are therefore studied with
increasing interest. Nonetheless, the microgel synthesis process and some of the resulting …

Kinetic prediction of functional group distributions in thermosensitive microgels

T Hoare, D McLean - The Journal of Physical Chemistry B, 2006 - ACS Publications
A kinetic model accounting for the copolymerization of up to four comonomers is applied to
predict both chain and radial functional group distributions in carboxylic-acid-functionalized …

Propagation Rate Coefficient for Radical Polymerization of N-Vinyl Pyrrolidone in Aqueous Solution Obtained by PLP−SEC

M Stach, I Lacik, D Chorvat Jr, M Buback… - …, 2008 - ACS Publications
Propagation rate coefficients, kp, of N-vinyl pyrrolidone (NVP) radical polymerization in
aqueous solution have been measured via the pulsed-laser polymerization-size exclusion …

Aqueous phase size-exclusion-chromatography used for PLP− SEC studies into free-radical propagation rate of acrylic acid in aqueous solution

I Lacík, S Beuermann, M Buback - Macromolecules, 2001 - ACS Publications
Pulsed laser polymerization (PLP) in conjunction with analysis of the resulting polymer by
size-exclusion-chromatography (SEC) was used to measure propagation rate coefficients …