Catalytic enantioselective aldol reactions
Recent developments in catalytic asymmetric aldol reactions have been summarized.
Enantioselective aldol reactions are important methods to synthesize β-hydroxy carbonyl …
Enantioselective aldol reactions are important methods to synthesize β-hydroxy carbonyl …
The direct catalytic asymmetric aldol reaction
Asymmetric aldol reactions are a powerful method for the construction of carbon–carbon
bonds in an enantioselective fashion. Historically this reaction has been performed in a …
bonds in an enantioselective fashion. Historically this reaction has been performed in a …
TEMPO-enabled electrochemical enantioselective oxidative coupling of secondary acyclic amines with ketones
ZH Wang, PS Gao, X Wang, JQ Gao… - Journal of the …, 2021 - ACS Publications
An electrochemical asymmetric coupling of secondary acyclic amines with ketones via a
Shono-type oxidation has been described, affording the corresponding amino acid …
Shono-type oxidation has been described, affording the corresponding amino acid …
Asymmetric aminocatalysis—gold rush in organic chemistry
Catalysis with chiral secondary amines (asymmetric aminocatalysis) has become a well‐
established and powerful synthetic tool for the chemo‐and enantioselective functionalization …
established and powerful synthetic tool for the chemo‐and enantioselective functionalization …
Asymmetric organocatalysis: from infancy to adolescence
A Dondoni, A Massi - Angewandte Chemie International …, 2008 - Wiley Online Library
After an initial period of validating asymmetric organocatalysis by using a wide range of
important model reactions that constitute the essential tools of organic synthesis, the time …
important model reactions that constitute the essential tools of organic synthesis, the time …
Visible‐light‐promoted asymmetric cross‐dehydrogenative coupling of tertiary amines to ketones by synergistic multiple catalysis
Reported herein is an unprecedented photocatalytic asymmetric cross‐dehydrogenative
coupling reaction between tertiary amines and simple ketones, and it proceeds by …
coupling reaction between tertiary amines and simple ketones, and it proceeds by …
Diastereodivergent catalysis
D Moser, TA Schmidt, C Sparr - JACS Au, 2023 - ACS Publications
Alongside enantioselective catalysis, synthetic chemists are often confronted by the
challenge of achieving catalyst control over the relative configuration to stereodivergently …
challenge of achieving catalyst control over the relative configuration to stereodivergently …
Catalytic asymmetric electrochemical oxidative coupling of tertiary amines with simple ketones
Catalytic asymmetric electrochemical C–H functionalization of simple ketones has been
developed. The transformation is realized by the combination of electrochemical oxidation …
developed. The transformation is realized by the combination of electrochemical oxidation …
Proline functionalized UiO-67 and UiO-68 type metal–organic frameworks showing reversed diastereoselectivity in aldol addition reactions
Functionalization of dicarboxylate linkers with proline was used to generate catalytically
active metal–organic frameworks (MOFs) for diastereoselective aldol addition. Due to high …
active metal–organic frameworks (MOFs) for diastereoselective aldol addition. Due to high …
Biomimetic asymmetric catalysis
X **ao, K Xu, ZH Gao, ZH Zhu, C Ye, B Zhao… - Science China …, 2023 - Springer
Enzymes are the core for biological transformations in nature. Their structures and functions
have drawn enormous attention from biologists as well as chemists since last century. The …
have drawn enormous attention from biologists as well as chemists since last century. The …