Catalytic enantioselective aldol reactions

Y Yamashita, T Yasukawa, WJ Yoo… - Chemical Society …, 2018 - pubs.rsc.org
Recent developments in catalytic asymmetric aldol reactions have been summarized.
Enantioselective aldol reactions are important methods to synthesize β-hydroxy carbonyl …

The direct catalytic asymmetric aldol reaction

BM Trost, CS Brindle - Chemical Society Reviews, 2010 - pubs.rsc.org
Asymmetric aldol reactions are a powerful method for the construction of carbon–carbon
bonds in an enantioselective fashion. Historically this reaction has been performed in a …

TEMPO-enabled electrochemical enantioselective oxidative coupling of secondary acyclic amines with ketones

ZH Wang, PS Gao, X Wang, JQ Gao… - Journal of the …, 2021 - ACS Publications
An electrochemical asymmetric coupling of secondary acyclic amines with ketones via a
Shono-type oxidation has been described, affording the corresponding amino acid …

Asymmetric aminocatalysis—gold rush in organic chemistry

P Melchiorre, M Marigo, A Carlone… - Angewandte Chemie …, 2008 - Wiley Online Library
Catalysis with chiral secondary amines (asymmetric aminocatalysis) has become a well‐
established and powerful synthetic tool for the chemo‐and enantioselective functionalization …

Asymmetric organocatalysis: from infancy to adolescence

A Dondoni, A Massi - Angewandte Chemie International …, 2008 - Wiley Online Library
After an initial period of validating asymmetric organocatalysis by using a wide range of
important model reactions that constitute the essential tools of organic synthesis, the time …

Visible‐light‐promoted asymmetric cross‐dehydrogenative coupling of tertiary amines to ketones by synergistic multiple catalysis

Q Yang, L Zhang, C Ye, S Luo, LZ Wu… - Angewandte Chemie …, 2017 - Wiley Online Library
Reported herein is an unprecedented photocatalytic asymmetric cross‐dehydrogenative
coupling reaction between tertiary amines and simple ketones, and it proceeds by …

Diastereodivergent catalysis

D Moser, TA Schmidt, C Sparr - JACS Au, 2023 - ACS Publications
Alongside enantioselective catalysis, synthetic chemists are often confronted by the
challenge of achieving catalyst control over the relative configuration to stereodivergently …

Catalytic asymmetric electrochemical oxidative coupling of tertiary amines with simple ketones

N Fu, L Li, Q Yang, S Luo - Organic letters, 2017 - ACS Publications
Catalytic asymmetric electrochemical C–H functionalization of simple ketones has been
developed. The transformation is realized by the combination of electrochemical oxidation …

Proline functionalized UiO-67 and UiO-68 type metal–organic frameworks showing reversed diastereoselectivity in aldol addition reactions

C Kutzscher, G Nickerl, I Senkovska, V Bon… - Chemistry of …, 2016 - ACS Publications
Functionalization of dicarboxylate linkers with proline was used to generate catalytically
active metal–organic frameworks (MOFs) for diastereoselective aldol addition. Due to high …

Biomimetic asymmetric catalysis

X **ao, K Xu, ZH Gao, ZH Zhu, C Ye, B Zhao… - Science China …, 2023 - Springer
Enzymes are the core for biological transformations in nature. Their structures and functions
have drawn enormous attention from biologists as well as chemists since last century. The …