Silver is a less expensive noble metal. Superior alkynophilicity due to π-coordination with
the carbon–carbon triple bond makes silver salts ideal catalysts for alkyne-based organic …

Carbon dioxide is a nontoxic, renewable, and abundant C1 source, whereas C− H bond
functionalization represents one of the most important approaches to the construction of …

Significant progress has been observed in recent years in the synthesis of allylic amines,
which are important building blocks in synthetic chemistry. Most of these processes are …

Carbon dioxide (CO 2) is the dominant greenhouse gas and the most abundant and
renewable C 1 resource. Therefore, the chemical fixation and conversion of CO 2 to high …

The carboxylation of terminal alkynes with CO 2 is an attractive route for CO 2 fixation and
conversion, and various homogeneous Cu (I) catalysts have been explored for the reaction …

Abstract The copper (I), silver (I), and gold (I) metals bind π‐ligands by σ‐bonding and π‐
back bonding interactions. These interactions were investigated using bidentate ancillary …

The fixation of CO2 as a carboxylic acid is a significant reaction for C–C bond formation in
organic synthesis. So far, besides C–H carboxylations using stoichiometric amounts of …

The mechanism and origin of stereoselectivity of silver-catalyzed hydroalkylation of alkynes
were computationally investigated at the B3LYP-D3BJ/6-311+ G (d, p)-SDD//B3LYP/6-31G …

Four novel N-heterocyclic carbene (NHC) silver complexes, I–IV, have been synthesized
and characterized. The single X-ray crystal diffraction data indicate a dinuclear solid-state …

C (sp)–H carboxylation with CO2 is an attractive route of CO2 utilization and is traditionally
promoted by transition metal catalysts, and organocatalysis for the conversion remains …