Electrochemical oxidative cross-coupling with hydrogen evolution: a green and sustainable way for bond formation
Summary Oxidative R 1–H/R 2–H cross-coupling represents an ideal way for the
construction of new chemical bonds. However, the bond formation with loss of H 2 is …
construction of new chemical bonds. However, the bond formation with loss of H 2 is …
Oxidative coupling between two hydrocarbons: an update of recent C–H functionalizations
C− C bond formation is a fundamental transformation in organic synthesis. The development
of new synthetic methodology could be considered as a way of pursuing a novel method for …
of new synthetic methodology could be considered as a way of pursuing a novel method for …
Silver-catalysed reactions of alkynes: recent advances
G Fang, X Bi - Chemical Society Reviews, 2015 - pubs.rsc.org
Silver is a less expensive noble metal. Superior alkynophilicity due to π-coordination with
the carbon–carbon triple bond makes silver salts ideal catalysts for alkyne-based organic …
the carbon–carbon triple bond makes silver salts ideal catalysts for alkyne-based organic …
Mechanistic view of Ru-catalyzed C–H bond activation and functionalization: computational advances
Ru-Catalyzed aromatic C–H bond activation and functionalization have emerged as
important topics because they have resulted in remarkable progress in organic synthesis …
important topics because they have resulted in remarkable progress in organic synthesis …
Cyclization Cascades via N-Amidyl Radicals toward Highly Functionalized Heterocyclic Scaffolds
N Fuentes, W Kong… - Journal of the …, 2015 - ACS Publications
The addition of a variety of radicals to the double bond of N-(arylsulfonyl) acrylamides can
trigger cyclization/aryl migration/desulfonylation cascades via amidyl radical intermediates …
trigger cyclization/aryl migration/desulfonylation cascades via amidyl radical intermediates …
Ag-catalyzed c–h/c–c bond functionalization
QZ Zheng, N Jiao - Chemical Society Reviews, 2016 - pubs.rsc.org
Silver, known and utilized since ancient times, is a coinage metal, which has been widely
used for various organic transformations in the past few decades. Currently, the silver …
used for various organic transformations in the past few decades. Currently, the silver …
Silver-Mediated Oxidative C–H/P–H Functionalization: An Efficient Route for the Synthesis of Benzo[b]phosphole Oxides
YR Chen, WL Duan - Journal of the American Chemical Society, 2013 - ACS Publications
A Ag-mediated C–H/P–H functionalization reaction of arylphosphine oxides with internal
alkynes was described for the direct preparation of benzo [b] phosphole oxides with a high …
alkynes was described for the direct preparation of benzo [b] phosphole oxides with a high …
External oxidant-free electrooxidative [3+ 2] annulation between phenol and indole derivatives
Abstract Intermolecular [3+ 2] annulation is one of the most straightforward approaches to
construct five membered heterocycles. However, it generally requires the use of …
construct five membered heterocycles. However, it generally requires the use of …
Silver-catalyzed isocyanide-alkyne cycloaddition: a general and practical method to oligosubstituted pyrroles.
J Liu, Z Fang, Q Zhang, Q Liu… - Angewandte Chemie …, 2013 - search.ebscohost.com
The article presents a study which examines a novel silver-catalyzed isocyanide-alkyne
cycloaddition. It states that the scope of internal alkynes that have been used in base-or …
cycloaddition. It states that the scope of internal alkynes that have been used in base-or …
Synthesis of pyrroles by click reaction: silver-catalyzed cycloaddition of terminal alkynes with isocyanides.
M Gao, C He, H Chen, R Bai, B Cheng… - Angewandte …, 2013 - search.ebscohost.com
The article presents a study on a silver-catalyzed click synthesis of pyrroles through co-
cyclization of terminal alkynes and isocyanides. It states that the silver salts could also …
cyclization of terminal alkynes and isocyanides. It states that the silver salts could also …