Coherence in Chemistry: Foundations and Frontiers
Coherence refers to correlations in waves. Because matter has a wave-particle nature, it is
unsurprising that coherence has deep connections with the most contemporary issues in …
unsurprising that coherence has deep connections with the most contemporary issues in …
Modelling exciton–phonon interactions in optically driven quantum dots
We provide a self-contained review of master equation approaches to modelling phonon
effects in optically driven self-assembled quantum dots. Coupling of the (quasi) two-level …
effects in optically driven self-assembled quantum dots. Coupling of the (quasi) two-level …
Open quantum system dynamics and the mean force Gibbs state
The dynamical convergence of a system to the thermal distribution, or Gibbs state, is a
standard assumption across all of the physical sciences. The Gibbs state is determined just …
standard assumption across all of the physical sciences. The Gibbs state is determined just …
Effective-Hamiltonian theory of open quantum systems at strong coupling
We present the reaction-coordinate polaron-transform (RCPT) framework for generating
effective-Hamiltonian models to treat nonequilibrium open quantum systems at strong …
effective-Hamiltonian models to treat nonequilibrium open quantum systems at strong …
Exact dynamics of nonadditive environments in non-Markovian open quantum systems
When a quantum system couples strongly to multiple baths, then it is generally no longer
possible to describe the resulting system dynamics by simply adding the individual effects of …
possible to describe the resulting system dynamics by simply adding the individual effects of …
Environmental dynamics, correlations, and the emergence of noncanonical equilibrium states in open quantum systems
Quantum systems are invariably open, evolving under surrounding influences rather than in
isolation. Standard open quantum system methods eliminate all information on the …
isolation. Standard open quantum system methods eliminate all information on the …
Energy transfer in structured and unstructured environments: Master equations beyond the Born-Markov approximations
We explore excitonic energy transfer dynamics in a molecular dimer system coupled to both
structured and unstructured oscillator environments. By extending the reaction coordinate …
structured and unstructured oscillator environments. By extending the reaction coordinate …
Exact states and spectra of vibrationally dressed polaritons
Strong coupling between light and matter is possible with a variety of organic materials. In
contrast to the simpler inorganic case, organic materials often have a complicated spectrum …
contrast to the simpler inorganic case, organic materials often have a complicated spectrum …
Implications of gauge freedom for nonrelativistic quantum electrodynamics
Gauge freedom in quantum electrodynamics (QED) outside of textbook regimes is reviewed.
It is emphasized that QED subsystems are defined relative to a choice of gauge. Each …
It is emphasized that QED subsystems are defined relative to a choice of gauge. Each …
Mechanism of delocalization-enhanced exciton transport in disordered organic semiconductors
Large exciton diffusion lengths generally improve the performance of organic semiconductor
devices, because they enable energy to be transported farther during the exciton lifetime …
devices, because they enable energy to be transported farther during the exciton lifetime …