Pd/Cu-catalyzed sonogashira cross-coupling polycondensation: A promising approach for synthesizing conjugated polymers with useful applications
Sonogashira cross-coupling polycondensation has been one of the most useful tools for the
construction of conjugated polymers with useful properties for multiple applications …
construction of conjugated polymers with useful properties for multiple applications …
Through-space conjugated polymers consisting of [2.2] paracyclophane
Y Morisaki, Y Chujo - Polymer Chemistry, 2011 - pubs.rsc.org
In this review, the synthesis and fundamental properties of [2.2] paracyclophane-containing
through-space conjugated polymers are introduced. By incorporating pseudo-para-, pseudo …
through-space conjugated polymers are introduced. By incorporating pseudo-para-, pseudo …
Probing substituent effects in aryl− aryl interactions using stereoselective Diels− Alder cycloadditions
Stereoselective Diels− Alder cycloadditions that probe substituent effects in aryl− aryl
sandwich complexes were studied experimentally and theoretically. Computations on model …
sandwich complexes were studied experimentally and theoretically. Computations on model …
Through‐space conjugated polymers based on cyclophanes
Y Morisaki, Y Chujo - Angewandte Chemie International …, 2006 - Wiley Online Library
Conjugated polymers display unique electronic and optical properties, which favor their use
in applications as optoelectronic materials and molecular devices. Despite the recent …
in applications as optoelectronic materials and molecular devices. Despite the recent …
Stimuli-responsive conjugated copolymers having electro-active azulene and bithiophene units in the polymer skeleton: Effect of protonation and p-do** on …
A series of stimuli-responsive conjugated copolymers containing alkylated bithiophene and
electroactive azulene in the polymer backbone was synthesized by oxidative polymerization …
electroactive azulene in the polymer backbone was synthesized by oxidative polymerization …
Excited mixed-valence states of symmetrical donor− acceptor− donor π systems
S Amthor, C Lambert, S Dümmler… - The Journal of …, 2006 - ACS Publications
We investigated the spectroscopic properties of a series of four bistriarylamine donor− π−
bridge-donor D− π− D compounds (dimers), composed of two asymmetric triarylamine …
bridge-donor D− π− D compounds (dimers), composed of two asymmetric triarylamine …
Solvatochromism of distyrylbenzene pairs bound together by [2.2] paracyclophane: evidence for a polarizable “through-space” delocalized state
A series of compounds were designed and synthesized to examine how through-space and
through-bond electron delocalization respond to solvent effects. The general strategy …
through-bond electron delocalization respond to solvent effects. The general strategy …
Cyclophane-containing polymers
Y Morisaki, Y Chujo - Progress in polymer science, 2008 - Elsevier
In spite of the remarkable progress of cyclophane chemistry, syntheses of polymers
containing cyclophane units in the main chain and side chain by utilizing the transannular π …
containing cyclophane units in the main chain and side chain by utilizing the transannular π …
Toward π-Conjugated Molecule Bundles: Synthesis of a Series of B,B',B''-Trianthryl-N,N',N''-triarylborazines and the Bundle Effects on Their Properties
A Wakamiya, T Ide, S Yamaguchi - Journal of the American …, 2005 - ACS Publications
As a prototype of a π-conjugated molecule bundled system, a series of B, B ', B ''-trianthryl-N,
N ', N ''-triarylborazine derivatives bearing various p-substituted phenyl groups (pR− C6H4 …
N ', N ''-triarylborazine derivatives bearing various p-substituted phenyl groups (pR− C6H4 …
Synthesis of π-stacked polymers on the basis of [2.2] paracyclophane
Y Morisaki, Y Chujo - Bulletin of the Chemical Society of Japan, 2009 - academic.oup.com
We synthesized π-stacked polymers by incorporating [2.2] paracyclophane units into
conjugated polymer backbones and developed corresponding through-space-conjugated …
conjugated polymer backbones and developed corresponding through-space-conjugated …