A new strategy for the direct cleavage of the C (sp3)–OH bond has been developed via
activation of free alcohols with neutral diphenyl boryl radical generated from sodium …

Heterocycles have maintained their popularity among researchers in all these years due to
their important activities in pharmaceuticals. Several reports on the synthesis of heterocycles …

C–N bond cross-couplings are fundamental in the field of organic chemistry. Herein,
silylboronate-mediated selective defluorinative cross-coupling of organic fluorides with …

Over the past several decades, the Zweifel olefination has emerged as one of the most
powerful and reliable tools for constructing C–C double bonds. This reaction features high …

Herein we report a transition metal-free approach for the regioselective functionalization of
benzylic C (sp 3) single bondH bonds in the presence of various heterocyclic amines as …

The synthesis of biaryl compounds by the transition-metal free coupling of arenes is an
important contemporary challenge, aiming to avoid the toxicity and cost profiles associated …

Tetrasubstituted olefins as a pivotal scaffold have been extensively employed in
pharmaceuticals, natural products, polymer chemistry, and material sciences and arouse …

Bis-and tris-pyridyl borate ligands containing pyridyl donor arms, a methylated boron cap,
and a fluorine-lined coordination pocket have been prepared and utilized in coinage metal …

In this study, we present an inexpensive, stable, and easily available boryl radical source
(BPh4Na) employed in a Halogen Atom Transfer (XAT) methodology. This mild and …

Intensified host-guest electronic interplay within stable metal-organic cages (MOCs)
presents great opportunities for applications in stimuli response and photocatalysis. Zr …