Polyoxometalates as heterogeneous catalysts for organic reactions

E Rafiee, S Eavani - Current Organic Chemistry, 2017 - ingentaconnect.com
Over the past decade, polyoxometalates (POMs) have attracted extensive attention as
homogeneous and heterogeneous catalysts or nanocatalysts for organic transformation. The …

Periodate-Mediated Aerobic Oxidation of Sulfides over a Bifunctional Porphyrin-polyoxometalate Catalyst: Photosensitized Singlet Oxygen Oxidation of Iodate to …

I Sardivand-Chegini, S Zakavi, MA Rezvani - Inorganic Chemistry, 2023 - ACS Publications
Regeneration of terminal oxidants by molecular oxygen in metal-catalyzed oxidations of
organic substrates has the advantage of avoiding the use of stoichiometric amounts of …

An environmentally benign three component one-pot synthesis of amidoalkyl naphthols using H4SiW12O40 as a recyclable catalyst

AR Supal, GS Gokavi - Journal of chemical sciences, 2010 - Springer
One pot synthesis of amidoalkyl naphthol by condensation of aromatic aldehydes, 2-
naphthol and amide/urea using silicotungstic acid as a catalyst is reported. The reaction was …

Efficient and selective oxidation of alcohols in water employing palladium supported nanomagnetic Fe3O4@hyperbranched polyethylenimine (Fe3O4@HPEI.Pd) …

A Ramazani, M Khoobi, F Sadri… - Applied …, 2018 - Wiley Online Library
Palladium immobilized magnetic nanoFe3O4@ hyperbranched polyethylenimine (Fe3O4@
HPEI. Pd) was prepared according to a simple and cost effective pathway and it was …

A new vanadium Schiff base complex as catalyst for oxidation of alcohols

M Bagherzadeh, M Amini - Journal of coordination chemistry, 2010 - Taylor & Francis
The monoanionic bidentate Schiff base, N-(phenolyl)-benzaldimine (HL), has been
employed to synthesize a new vanadium (IV) complex of general composition [VO (L) …

A DFT study on the effect of metal, anion charge, heteroatom and structure upon the relative basicities of polyoxoanions

JA Fernández, X López, JM Poblet - Journal of Molecular Catalysis A …, 2007 - Elsevier
In many reactions catalyzed by polyoxoanions, the first step involves attaching a proton at
the anion so that the activated species can react with the substrate. The present study …

A new Keggin-type polyoxometalate catalyst for degradation of aqueous organic contaminants

A Olgun, AT Colak, İH Gübbük, O Şahin… - Journal of Molecular …, 2017 - Elsevier
In this study, a new polyoxometalate, K 16 [Ni (H 2 O) 6] 2 [BW 12 O 40] 4· 48H 2 O (1) was
synthesized at room temperature and characterized by X-ray single crystal diffractions …

[HTML][HTML] Selective aqueous oxidation of alcohols catalyzed by copper (II) phthalocyanine nanoparticles

S Kheirjou, R Kheirjou, AH Rezayan… - Comptes Rendus …, 2016 - Elsevier
A new catalyst based on metallophthalocyanine nanoparticles has been synthesized and
characterized by scanning electron microscopy (SEM). The aqueous oxidation of alcohols to …

Immobilized Sandwich-Type Polyoxometalates [Mn4(XW9O34)2]n− on Tb-Doped TiO2 Nanoparticles as Efficient and Selective Catalysts in the Oxidation of …

S Gholamyan, R Khoshnavazi, A Rostami, L Bahrami - Catalysis Letters, 2017 - Springer
Sandwich-type polyoxometalates of [M 4 (XW 9 O 34) 2] n−(M= Mn 2+, Cu 2+, Zn 2+, X= Ge
4+, P 5+, As 5+) supported on Ln-doped TiO 2 (Ln= Nd 3+, Sm 3+, Tb 3+ and Dy 3+) …

Electrocatalytic performance of carbon supported Pd catalyst modified with Keggin type of Sn-substituted polyoxometalatate for formic acid oxidization

Y Ji, L Shen, A Wang, M Wu, Y Tang, Y Chen… - Journal of Power …, 2014 - Elsevier
Abstract The carbon supported Pd (Pd/C) catalyst modified by the new polyoxometalate with
Keggin type of Sn-Substituted structure K 7 Co II W 11 O 39 Sn IV OH (Pd/C–K 7) catalyst is …