Metal‐Organic Frameworks for Photocatalytic Water Splitting and CO2 Reduction

K Sun, Y Qian, HL Jiang - Angewandte Chemie, 2023 - Wiley Online Library
Photocatalytic water splitting and carbon dioxide (CO2) reduction provide promising
solutions to global energy and environmental issues. In recent years, metal‐organic …

Coordination engineering in single-site catalysts: General principles, characterizations, and recent advances

H Wang, T Yang, J Wang, Z Zhou, Z Pei, S Zhao - Chem, 2024 - cell.com
Single-site catalysts (SSCs) have long been considered to be promising candidates for
heterogeneous catalysis due to the maximum exposure of metal sites at the catalytic …

Heteroatom‐Doped Ag25 Nanoclusters Encapsulated in Metal–Organic Frameworks for Photocatalytic Hydrogen Production

H Wang, X Zhang, W Zhang, M Zhou… - Angewandte Chemie …, 2024 - Wiley Online Library
Atomically precise metal nanoclusters (NCs) with unique optical properties and abundant
catalytic sites are promising in photocatalysis. However, their light‐induced instability and …

Manipulating the Spin State of Co Sites in Metal–Organic Frameworks for Boosting CO2 Photoreduction

K Sun, Y Huang, Q Wang, W Zhao… - Journal of the …, 2024 - ACS Publications
Photocatalytic CO2 reduction holds great potential for alleviating global energy and
environmental issues, where the electronic structure of the catalytic center plays a crucial …

Linker Engineering of Sandwich‐Structured Metal–Organic Framework Composites for Optimized Photocatalytic H2 Production

S Wang, Z Ai, X Niu, W Yang, R Kang, Z Lin… - Advanced …, 2023 - Wiley Online Library
While the microenvironment around catalytic sites is recognized to be crucial in
thermocatalysis, its roles in photocatalysis remain subtle. In this work, a series of sandwich …

Water‐Stable High‐Entropy Metal‐Organic Framework Nanosheets for Photocatalytic Hydrogen Production

S Qi, K Zhu, T Xu, H Zhang, X Guo, J Wang… - Advanced …, 2024 - Wiley Online Library
Metal‐organic frameworks (MOFs) have emerged as promising platforms for photocatalytic
hydrogen evolution reaction (HER) due to their fascinating physiochemical properties …

Thermocatalytic Conversion of CO2 to Valuable Products Activated by Noble‐Metal‐Free Metal‐Organic Frameworks

SL Hou, J Dong, XY Zhao, XS Li, FY Ren… - Angewandte Chemie …, 2023 - Wiley Online Library
Thermocatalysis of CO2 into high valuable products is an efficient and green method for
mitigating global warming and other environmental problems, of which Noble‐metal‐free …

A Dual-Purpose Ce(III)–Organic Framework with Amine Groups and Open Metal Sites: Third-Order Nonlinear Optical Activity and Catalytic CO2 Fixation

Y Hu, R Abazari, S Sanati, M Nadafan… - … Applied Materials & …, 2023 - ACS Publications
The present work focuses on the synthesis and properties of a novel multifunctional cerium
(III) MOF,[Ce2 (data) 3 (DMF) 4]· DMF (data2–: 2, 5-diaminoterephthalate), abbreviated as …

Copper(II) Schiff-Base Complex Modified UiO-66-NH2(Zr) Metal–Organic Framework Catalysts for Knoevenagel Condensation–Michael Addition–Cyclization …

F Ghobakhloo, D Azarifar, M Mohammadi… - Inorganic …, 2022 - ACS Publications
The synthesis of five-and six-membered oxygen-and nitrogen-containing heterocycles has
been regarded as the most fundamental issue in organic chemistry and chemical industry …

Precise Regulation of the Coordination Environment of Single Co(II) Sites in a Metal–Organic Framework for Boosting CO2 Photoreduction

J Wang, K Sun, D Wang, X Niu, Z Lin, S Wang… - ACS …, 2023 - ACS Publications
While the coordination environment around catalytic metal sites plays a crucial role in
catalysis, its precise design and modulation still remain a challenge. Herein, the coordinated …