Recent Advances in Alkenyl sp2 C–H and C–F Bond Functionalizations: Scope, Mechanism, and Applications
MZ Lu, J Goh, M Maraswami, Z Jia, JS Tian… - Chemical …, 2022 - ACS Publications
Alkenes and their derivatives are featured widely in a variety of natural products,
pharmaceuticals, and advanced materials. Significant efforts have been made toward the …
pharmaceuticals, and advanced materials. Significant efforts have been made toward the …
Increasing catalyst efficiency in C− H activation catalysis
T Gensch, MJ James, T Dalton… - Angewandte Chemie …, 2018 - Wiley Online Library
C− H activation reactions with high catalyst turnover numbers are still very rare in the
literature and 10 mol% is a common catalyst loading in this field. We offer a representative …
literature and 10 mol% is a common catalyst loading in this field. We offer a representative …
Weak-coordination in C–H bond functionalizations catalyzed by 3d metals
Transition-metal-catalyzed C–H bond functionalizations have had an enormous influence on
organic synthesis in recent times. However, the use of low-abundance 4d and 5d metals is …
organic synthesis in recent times. However, the use of low-abundance 4d and 5d metals is …
Cp* Co (III)/MPAA-catalyzed enantioselective amidation of ferrocenes directed by thioamides under mild conditions
YH Liu, PX Li, QJ Yao, ZZ Zhang, DY Huang… - Organic …, 2019 - ACS Publications
Cp* Cobalt (III)-catalyzed enantioselective C–H amidation of ferrocenes using
monoprotected amino acids (MPAAs) as chiral ligands was developed. The reaction was …
monoprotected amino acids (MPAAs) as chiral ligands was developed. The reaction was …
Triptycenyl Sulfide: A Practical and Active Catalyst for Electrophilic Aromatic Halogenation Using N-Halosuccinimides
A Lewis base catalyst Trip-SMe (Trip= triptycenyl) for electrophilic aromatic halogenation
using N-halosuccinimides (NXS) is introduced. In the presence of an appropriate activator …
using N-halosuccinimides (NXS) is introduced. In the presence of an appropriate activator …
Ni‐Catalyzed Chelation‐Assisted Direct Functionalization of Inert C—H Bonds
YH Liu, YN **a, BF Shi - Chinese Journal of Chemistry, 2020 - Wiley Online Library
During the last two decades, impressive advancements have been achieved in transition
metal‐catalyzed chelation‐assisted C—H functionalization reaction. While reactions in this …
metal‐catalyzed chelation‐assisted C—H functionalization reaction. While reactions in this …
Recent Advances in First‐Row Transition‐Metal‐Mediated C− H Halogenation of (Hetero) arenes and Alkanes
The ubiquity of carbon halogen bonds in the structural core of numerous biomolecules and
pharmaceuticals along with their role as synthetic precursors in various organic reactions …
pharmaceuticals along with their role as synthetic precursors in various organic reactions …
Asymmetric Palladium-Catalyzed Aminochlorination of Unactivated Alkenes
Z Wang, C Hou, P Chen - Organic letters, 2023 - ACS Publications
A novel Pd-catalyzed enantioselective aminochlorination of alkenes via a 6-endo cyclization
is reported herein, which provides easy access to a wide array of structurally diverse 3 …
is reported herein, which provides easy access to a wide array of structurally diverse 3 …
Palladium-Catalyzed Electrochemical Iodination of 1-Arylpyridine N-Oxides
H Zhou, M Miyasaka, YH Wang, T Kochi… - The Journal of Organic …, 2024 - ACS Publications
The palladium-catalyzed C–H iodination of 1-arylpyridine N-oxides proceeded under
electrochemical oxidation conditions using I2 as an iodine source. The reaction of …
electrochemical oxidation conditions using I2 as an iodine source. The reaction of …
DABCO as a practical catalyst for aromatic halogenation with N-halosuccinimides
H Xu, L Hu, G Zhu, Y Zhu, Y Wang, ZG Wu, Y Zi… - RSC …, 2022 - pubs.rsc.org
A simple and practical synthetic approach for synthesis of aromatic halides is developed.
Simple Lewis base, DABCO, is used as the catalyst. This arene halogenation process …
Simple Lewis base, DABCO, is used as the catalyst. This arene halogenation process …