Metallaphotoredox catalysis for sp 3 C–H functionalizations through hydrogen atom transfer (HAT)

J Zhang, M Rue** - Chemical Society Reviews, 2023 - pubs.rsc.org
In recent years, the integration of photocatalytic hydrogen atom transfer (HAT) with transition
metal catalysis has emerged as a formidable strategy for the construction of C (sp3)–carbon …

Visible light-induced transition metal catalysis

KPS Cheung, S Sarkar, V Gevorgyan - Chemical reviews, 2021 - ACS Publications
In recent years, visible light-induced transition metal catalysis has emerged as a new
paradigm in organic photocatalysis, which has led to the discovery of unprecedented …

Photoactive copper complexes: properties and applications

J Beaudelot, S Oger, S Perusko, TA Phan… - Chemical …, 2022 - ACS Publications
Photocatalyzed and photosensitized chemical processes have seen growing interest
recently and have become among the most active areas of chemical research, notably due …

Photocatalysis in the life science industry

L Candish, KD Collins, GC Cook, JJ Douglas… - Chemical …, 2021 - ACS Publications
In the pursuit of new pharmaceuticals and agrochemicals, chemists in the life science
industry require access to mild and robust synthetic methodologies to systematically modify …

Electrochemically driven cross-electrophile coupling of alkyl halides

W Zhang, L Lu, W Zhang, Y Wang, SD Ware… - Nature, 2022 - nature.com
Recent research in medicinal chemistry has suggested that there is a correlation between
an increase in the fraction of sp 3 carbons—those bonded to four other atoms—in drug …

Photoinduced organocatalyzed atom transfer radical polymerization (O-ATRP): precision polymer synthesis using organic photoredox catalysis

DA Corbin, GM Miyake - Chemical reviews, 2021 - ACS Publications
The development of photoinduced organocatalyzed atom transfer radical polymerization (O-
ATRP) has received considerable attention since its introduction in 2014. Expanding on …

Identification of alkoxy radicals as hydrogen atom transfer agents in Ce-catalyzed C–H functionalization

Q An, YY **ng, R Pu, M Jia, Y Chen, A Hu… - Journal of the …, 2022 - ACS Publications
The intermediacy of alkoxy radicals in cerium-catalyzed C–H functionalization via H-atom
abstraction has been unambiguously confirmed. Catalytically relevant Ce (IV)–alkoxide …

Generation of alkyl radicals: from the tyranny of tin to the photon democracy

S Crespi, M Fagnoni - Chemical reviews, 2020 - ACS Publications
Alkyl radicals are key intermediates in organic synthesis. Their classic generation from alkyl
halides has a severe drawback due to the employment of toxic tin hydrides to the point that …

Visible‐light‐induced homolysis of earth‐abundant metal‐substrate complexes: A complementary activation strategy in photoredox catalysis

Y Abderrazak, A Bhattacharyya… - Angewandte Chemie …, 2021 - Wiley Online Library
The mainstream applications of visible‐light photoredox catalysis predominately involve
outer‐sphere single‐electron transfer (SET) or energy transfer (EnT) processes of precious …

Degradation of plastic wastes to commercial chemicals and monomers under visible light

J Meng, Y Zhou, D Li, X Jiang - Science Bulletin, 2023 - Elsevier
Plastics are playing an incrementally extensive and irreplaceable role in human life, but with
alarming cyclic unsustainability. Numerous attempts have been undertaken to recycle …