Although known for over 90 years, only in the past two decades has the chemistry of diboron
(4) compounds been extensively explored. Many interesting structural features and reaction …

Recent Advances in the Preparation and Application of Allylboron Species in Organic
Synthesis | Journal of the American Chemical Society Recently Viewedclose modal ACS ACS …

There are few examples of catalytic transfer hydrogenations of simple alkenes and alkynes
that use water as a stoichiometric H or D atom donor. We have found that diboron reagents …

The combination of a palladium complex with a chiral phosphoramidite ligand and a chiral
phosphoric acid enables the first highly efficient asymmetric allylic alkylation of pyrazol-5 …

Transformations that entail catalytic generation of reactive entities for in situ use in
stereoselective synthesis are in high demand;[1] such processes are more efficient and …

An orthogonal set of catalyst systems has been developed for the Suzuki–Miyaura coupling
of 3, 3-disubstituted and 3-monosubstituted allylboronates with (hetero) aryl halides. These …

Formaldehyde (FA) is a reactive signaling molecule that is continuously produced through a
number of central biological pathways spanning epigenetics to one-carbon metabolism. On …

The cooperation of multiple catalytic components is a powerful tool for intermolecular bond
formation, specifically, cross-coupling reactions. Supported metal catalysts have interfacial …

A novel and efficient protocol for the synthesis of diarylallyl-functionalized phosphonates,
phosphinates, and phosphine oxides through the zinc-catalyzed dehydroxylative …

Allylboration of ketones with γ-disubstituted allylboronic acids is performed in the presence
of chiral BINOL derivatives. The reaction is suitable for single-step creation of adjacent …