Bonding and structure trends of thiosemicarbazone derivatives of metals—an overview

TS Lobana, R Sharma, G Bawa, S Khanna - Coordination Chemistry …, 2009 - Elsevier
This review describes the coordination chemistry of thiosemicarbazones and covers all the
metals for which complexes are reported. The coordination compounds of d-block, p-block …

Recent developments on the potential biological applications of transition metal complexes of thiosemicarbazone derivatives

V Singh, VNV Palakkeezhillam, V Manakkadan… - Polyhedron, 2023 - Elsevier
This review talks about the synthesis, and coordination chemistry of thiosemicarbazone and
its bonding with transition metals like copper, nickel, zinc, palladium, and ruthenium and …

A novel water soluble ligand bridged cobalt (II) coordination polymer of 2-oxo-1, 2-dihydroquinoline-3-carbaldehyde (isonicotinic) hydrazone: evaluation of the DNA …

DS Raja, NSP Bhuvanesh, K Natarajan - Dalton Transactions, 2012 - pubs.rsc.org
A novel water soluble ligand-bridged cobalt (II) coordination polymer has been synthesized
by reacting the new ligand, 2-oxo-1, 2-dihydroquinoline-3-carbaldehyde (isonicotinic) …

Polynuclear zinc (II) complexes of thiosemicarbazone: Synthesis, X-ray structure and biological evaluation

M Mohanty, A Banerjee, S Biswal, A Horn Jr… - Journal of Inorganic …, 2020 - Elsevier
Two new dimeric Zn (II)([{ZnL 1 (DMSO 2)} 2]· DMSO (1),[{ZnL 2 Cl} 2](2)) and a novel
tetrameric Zn (II) complex ([(Zn 2 L 3) 2 (μ–OAc) 2 (μ 3–O) 2](3)), where H 2 L 1= 4–(p …

Impact of metal coordination on cytotoxicity of 3-aminopyridine-2-carboxaldehyde thiosemicarbazone (triapine) and novel insights into terminal dimethylation

CR Kowol, R Trondl, P Heffeter, VB Arion… - Journal of medicinal …, 2009 - ACS Publications
The first metal complexes of 3-aminopyridine-2-carboxaldehyde thiosemicarbazone
(Triapine) were synthesized. Triapine was prepared by a novel three-step procedure in 64 …

Synthesis, X-ray structure and in vitro cytotoxicity studies of Cu (I/II) complexes of thiosemicarbazone: special emphasis on their interactions with DNA

A Chakraborty, SP Dash, AK Panda, R Acharyya… - Dalton …, 2015 - pubs.rsc.org
4-(pX-phenyl) thiosemicarbazone of napthaldehyde {where X= Cl (HL1) and X= Br (HL2)},
thiosemicarbazone of quinoline-2-carbaldehyde (HL3) and 4-(p-fluorophenyl) …

Synthesis, crystal structure analysis, spectral characterization and nonlinear optical exploration of potent thiosemicarbazones based compounds: A DFT refine …

R Jawaria, M Hussain, M Khalid, MU Khan… - Inorganica Chimica …, 2019 - Elsevier
The thiosemicarbazones have exciting biological and nonlinear optical (NLO) applications.
The present study reports detail experimental and computational studies of three novel …

Single Crystal Sub‐Nanometer Sized Cu6(SR)6 Clusters: Structure, Photophysical Properties, and Electrochemical Sensing

X Gao, S He, C Zhang, C Du, X Chen, W **ng… - Advanced …, 2016 - Wiley Online Library
Organic ligand‐protected metal nanoclusters have attracted extensively attention owing to
their atomically precise composition, determined atom‐packing structure and the fascinating …

Chemical and biological evaluation of thiosemicarbazone-bearing heterocyclic metal complexes

AI Matesanz, JM Herrero… - Current topics in medicinal …, 2021 - benthamdirect.com
Thiosemicarbazones (TSCNs) constitute a broad family of compounds (R1R2C= N-NH-C (S)-
NR3R4), particularly attractive because many of them display some biological activity …

Copper (I) and silver (I) complexes of anthraldehyde thiosemicarbazone: synthesis, structure elucidation, in vitro anti-tuberculosis/cytotoxic activity and interactions …

A Khan, K Paul, I Singh, JP Jasinski… - Dalton …, 2020 - pubs.rsc.org
A reaction of copper (I) halides (X= I, Br, Cl) and silver (I) halides with 9-anthraldehyde
thiosemicarbazone (9-Hanttsc, H1L) and triphenylphosphine produced halogen-bridged …