Sustainable developments in polyolefin chemistry: Progress, challenges, and outlook

XY Wang, Y Gao, Y Tang - Progress in Polymer Science, 2023 - Elsevier
Polyolefins are the largest-scale synthetic plastics and play a key role in modern society.
Their production consumes huge amounts of fossil-derived monomer feedstocks, which …

Catalytic Upcycling of Polyolefins

J Sun, J Dong, L Gao, YQ Zhao, H Moon… - Chemical …, 2024 - ACS Publications
The large production volumes of commodity polyolefins (specifically, polyethylene,
polypropylene, polystyrene, and poly (vinyl chloride)), in conjunction with their low unit …

Catalytic deconstruction of waste polyethylene with ethylene to form propylene

RJ Conk, S Hanna, JX Shi, J Yang, NR Ciccia, L Qi… - Science, 2022 - science.org
The conversion of polyolefins to monomers would create a valuable carbon feedstock from
the largest fraction of waste plastic. However, breakdown of the main chains in these …

Hydrogen production, storage, and transportation: recent advances

MM Rampai, CB Mtshali, NS Seroka, L Khotseng - RSC advances, 2024 - pubs.rsc.org
One such technology is hydrogen-based which utilizes hydrogen to generate energy without
emission of greenhouse gases. The advantage of such technology is the fact that the only by …

Recent progress in the chemical upcycling of plastic wastes

X Chen, Y Wang, L Zhang - ChemSusChem, 2021 - Wiley Online Library
The massive generation of plastic wastes without satisfactory treatment has induced severe
environmental problems and gained increasing attentions. In this Minireview, recent …

Solar-driven photocatalysis for recycling and upcycling plastics

R Cao, D **ao, M Wang, Y Gao, D Ma - Applied Catalysis B: Environmental, 2024 - Elsevier
The widespread use of plastics in modern societies generates huge amounts of plastic
waste. With a view toward sustainability, researchers are now seeking strategies for …

Disordered, Sub-Nanometer Ru Structures on CeO2 are Highly Efficient and Selective Catalysts in Polymer Upcycling by Hydrogenolysis

L Chen, LC Meyer, L Kovarik, D Meira… - ACS …, 2022 - ACS Publications
Nondegradable polyolefin plastics pose severe environmental threats and thus demand
efficient upcycling technologies. In this work, we discovered that low-loading (≤ 0.25 wt%) …

Nanocatalyzed upcycling of the plastic wastes for a circular economy

C Wang, H Han, Y Wu, D Astruc - Coordination Chemistry Reviews, 2022 - Elsevier
Plastics are now essential components in our daily life, but they have also raised a waste
crisis and environmental pollution issues. The traditional plastic waste treatments rely on …

Effect of reaction conditions on the hydrogenolysis of polypropylene and polyethylene into gas and liquid alkanes

L Chen, Y Zhu, LC Meyer, LV Hale, TT Le… - Reaction Chemistry & …, 2022 - pubs.rsc.org
Hydrogenolysis of polypropylene (PP) and polyethylene (PE) provides a pathway to convert
these plastics into smaller hydrocarbons at relatively low temperature. Among carbon (C) …

Threading-the-Needle: Compatibilization of HDPE/iPP blends with butadiene-derived polyolefin block copolymers

L Shen, GD Gorbea, E Danielson, S Cui… - Proceedings of the …, 2023 - pnas.org
Management of the plastic industry is a momentous challenge, one that pits enormous
societal benefits against an accumulating reservoir of nearly indestructible waste. A …