A new golden age for donor–acceptor cyclopropanes

TF Schneider, J Kaschel… - Angewandte Chemie …, 2014 - Wiley Online Library
The effective use of ring strain has been applied to considerable advantage for the
construction of complex systems. The focus here is directed towards cyclopropanes as …

Recent advances in the preparation and application of allylboron species in organic synthesis

C Diner, KJ Szabo - Journal of the American Chemical Society, 2017 - ACS Publications
Recent Advances in the Preparation and Application of Allylboron Species in Organic
Synthesis | Journal of the American Chemical Society Recently Viewedclose modal ACS ACS …

Asymmetric Preparation of Polysubstituted Cyclopropanes Based on Direct Functionalization of Achiral Three-Membered Carbocycles: Focus Review

L Dian, I Marek - Chemical reviews, 2018 - ACS Publications
In addition to the appealing synthetic transformations that cyclopropanes present, they are
also part of larger molecular structures that possess a wide range of biological properties …

Catalysis by palladium pincer complexes

N Selander, KJ Szabó - Chemical Reviews, 2011 - ACS Publications
1.1. General Considerations Palladium catalysis is one of the most important synthetic tools
in modern organic synthesis. A particularly attractive synthetic feature of palladium catalysis …

Designing Pd–N-Heterocyclic Carbene Complexes for High Reactivity and Selectivity for Cross-Coupling Applications

RDJ Froese, C Lombardi, M Pompeo… - Accounts of Chemical …, 2017 - ACS Publications
Conspectus Over the past decade, the use of Pd–NHC complexes in cross-coupling
applications has blossomed, and reactions that were either not previously possible or …

Stereospecific couplings of secondary and tertiary boronic esters

D Leonori, VK Aggarwal - Angewandte Chemie International …, 2015 - Wiley Online Library
This Minireview highlights advances in the Suzuki–Miyaura cross‐coupling of secondary
boron reagents for the creation of C C bonds with control of stereochemistry. It also …

Structure, properties, and preparation of boronic acid derivatives. Overview of their reactions and applications

DG Hall - Boronic acids: preparation and applications in …, 2005 - Wiley Online Library
Structurally, boronic acids are trivalent boron-containing organic compounds that possess
one alkyl substituent (ie, a C–B bond) and two hydroxyl groups to fill the remaining valences …

Direct Cross‐Coupling of Allylic C(sp3)−H Bonds with Aryl‐ and Vinylbromides by Combined Nickel and Visible‐Light Catalysis

L Huang, M Rue** - Angewandte Chemie, 2018 - Wiley Online Library
An efficient protocol for the direct allylic C (sp3)− H bond activation of unactivated tri‐and
tetrasubstituted alkenes and their functionalization with aryl‐and vinylbromides by nickel …

Synthetic applications of vinyl cyclopropane opening

M Meazza, H Guo, R Rios - Organic & Biomolecular Chemistry, 2017 - pubs.rsc.org
Vinyl cyclopropanes are amongst the most useful building blocks in organic synthesis. Their
easy opening and capacity to generate dipoles have been exploited for the synthesis of …

Iron-catalyzed 1, 4-hydroboration of 1, 3-dienes

JY Wu, B Moreau, T Ritter - Journal of the American Chemical …, 2009 - ACS Publications
Iron-Catalyzed 1,4-Hydroboration of 1,3-Dienes | Journal of the American Chemical Society
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