Smart organic materials based on macrocycle hosts

XY Lou, S Zhang, Y Wang, YW Yang - Chemical Society Reviews, 2023 - pubs.rsc.org
Innovative design of smart organic materials is of great importance for the advancement of
modern technology. Macrocycle hosts, possessing cyclic skeletons, intrinsic cavities, and …

Recent Advances of Organic Cocrystals in Emerging Cutting‐Edge Properties and Applications

X Wang, Z Wang, X Wang, F Kang, Q Gu… - Angewandte …, 2024 - Wiley Online Library
Organic cocrystals, representing one type of new functional materials, have gathered
significant interest in various engineering areas. Owing to their diverse stacking modes, rich …

A general supramolecular strategy for fabricating full-color-tunable thermally activated delayed fluorescence materials

N Xue, HY Zhou, Y Han, M Li, HY Lu… - Nature …, 2024 - nature.com
Develo** a facile and feasible strategy to fabricate thermally activated delayed
fluorescence materials exhibiting full-color tunability remains an appealing yet challenging …

Grinding-induced supramolecular charge-transfer assemblies with switchable vapochromism toward haloalkane isomers

JR Wu, G Wu, D Li, MH Li, Y Wang, YW Yang - Nature Communications, 2023 - nature.com
Synthetic macrocycles have proved to be of great application value in functional charge-
transfer systems in the solid state in recent years. Here we show a switchable on-off type …

Naphth [4] arene: Synthesis, Conformations, and Application in Color‐Tunable Supramolecular Crystalline Assemblies

MJ Gu, XN Han, WC Guo, Y Han… - Angewandte Chemie, 2023 - Wiley Online Library
Although the chemistry of macrocyclic arenes has seen rapid development in recent years,
the synthesis of new macrocyclic arenes from aromatic rings with no directing groups …

Macrocycle‐Based Charge Transfer Cocrystals with Dynamically Reversible Chiral Self‐Sorting Display Chain Length‐Selective Vapochromism to Alkyl Ketones

MJ Gu, WC Guo, XN Han, Y Han… - Angewandte Chemie …, 2024 - Wiley Online Library
Chirality‐driven self‐sorting plays an essential role in controlling the biofunction of
biosystems, such as the chiral double‐helix structure of DNA from self‐recognition by …

Separation of cyclohexanone and cyclohexanol by adaptive pillar [5] arene cocrystals accompanied by vapochromic behavior

B Li, Y Wang, L Liu, M Dong, C Li - JACS Au, 2023 - ACS Publications
The separation of cyclohexanone (CHA-one) and cyclohexanol (CHA-ol) mixtures is of great
importance in the chemical industry. Current technology exploits multiple steps of energy …

Separation of p-Xylene from C8 Alkylaromatics by Nonporous Adaptive Crystals of Leggero Pillar[4]arene[1]quinone

G Zhang, K Zhang, XY Lou, X Li, CL Song… - ACS Materials …, 2023 - ACS Publications
The separation and purification of C8 aromatics under nonthermal conditions remain a
significant challenge in the chemical industry. Here, we report a new leggero pillararene …

Structurally diverse macrocycle co-crystals for solid-state luminescence modulation

B Li, L Liu, Y Wang, K Liu, Z Zheng, S Sun, Y Hu… - Nature …, 2024 - nature.com
Organic co-crystals offer an opportunity to fabricate organic functional materials. Traditional
co-crystals are generally packed following the segregated or mixed stacking mode, leading …

Highly selective separation of toluene/methylcyclohexane based on pagoda [5] arene nonporous adaptive crystals

Z Liu, M Li, S Fang, L Shao, B Hua… - Organic Chemistry …, 2024 - pubs.rsc.org
Highly selective separation of toluene (Tol) over methylcyclohexane (MCH) has been
achieved by utilizing nonporous adaptive crystals of pagoda [5] arene P5. Specifically, P5 …