Most of the methods for the synthesis of functionalized enamides from ynamides were
developed in the last two decades showing the contemporary interest in the exploration of …

Ynamides are electron-rich alkynes with a carbon–carbon triple bond directly attached to the
nitrogen atom bearing an electron-withdrawing group. This unique structure renders diverse …

An atom-economic protocol for the efficient and highly chemo-and stereoselective trans-
hydroarylation of ynamides with hydroxyarenes catalyzed by B (C6F5) 3 has been …

Alkoxy-substituted enamides are often used as synthetic intermediates due to their special
reactivity. To the best our knowledge, the biological activity of alkoxy-substituted amines has …

Ynamides/arylynamines are challenging substrates for oxyacetoxylation, especially due to
various reactive sites of the N‐heteroaryl ring. Herein, we report a metal‐free PhI (OAc) 2 …

An atom-economical and efficient route for the synthesis of alkynylphosphonates and
ynamides by aerobic oxidative alkynylation of H-phosphonates and amides with both …

Herein we describe a self-acid-enabled chemo-, regio-, and stereospecific cis-
hydrophenoxylation of ynamides under reagent-free conditions. The presence of a non …

Yndiamides, N, N-disubstituted alkynes, are versatile building blocks for the synthesis of
nitrogen-containing organic molecules. Unlike ynamides, relatives that are inherently …

This chapter highlights the transition metal (TM)-catalyzed difunctionalization, cyclization,
hydrofunctionalization, and related reactions of ynamides. These elementary reactions …

In Chapter 1, an introduction to fluorine chemistry is given. The physical properties of
fluorine are discussed, and examples of how the introduction of fluorine into a molecule can …