[HTML][HTML] Magnetic molecules on surfaces: SMMs and beyond

G Gabarró-Riera, G Aromí, EC Sañudo - Coordination Chemistry Reviews, 2023 - Elsevier
In this critical review we cover the state of the art of surface deposition of complex magnetic
molecules. Deposition methods are reviewed, as well as the most used types of surfaces …

Advanced hematite nanomaterials for newly emerging applications

H Wan, L Hu, X Liu, Y Zhang, G Chen, N Zhang… - Chemical …, 2023 - pubs.rsc.org
Because of the combined merits of rich physicochemical properties, abundance, low toxicity,
etc., hematite (α-Fe2O3), one of the most chemically stable compounds based on the …

Air-stable chiral single-molecule magnets with record anisotropy barrier exceeding 1800 K

Z Zhu, C Zhao, T Feng, X Liu, X Ying, XL Li… - Journal of the …, 2021 - ACS Publications
Design and synthesis of air-stable and easily tailored high-performance single-molecule
magnets (SMMs) are of great significance toward the implementation of SMMs in molecular …

Strategies to quench quantum tunneling of magnetization in lanthanide single molecule magnets

A Swain, T Sharma, G Rajaraman - Chemical Communications, 2023 - pubs.rsc.org
Enhancing blocking temperature (TB) is one of the holy grails in Single Molecule Magnets
(SMMs), as any future potential application in this class of molecules is directly correlated to …

Monovalent lanthanide (I) in borozene complexes

WL Li, TT Chen, WJ Chen, J Li, LS Wang - Nature Communications, 2021 - nature.com
Lanthanide (Ln) elements are generally found in the oxidation state+ II or+ III, and a few
examples of+ IV and+ V compounds have also been reported. In contrast, monovalent Ln (+ …

Blue-Emitting Ligand-Mediated Assembly of Rare-Earth MOFs toward White-Light Emission, Sensing, Magnetic, and Catalytic Studies

K Manna, JP Sutter, S Natarajan - Inorganic Chemistry, 2022 - ACS Publications
New lanthanide carboxylate compounds with two-(2D) and three-dimensional (3D)
structures have been prepared by employing 2, 5-bis (prop-2-yn-1-yloxy) terephthalic acid …

Photocontrollable magnetism and photoluminescence in a binuclear dysprosium anthracene complex

XD Huang, XF Ma, T Shang, YQ Zhang… - Inorganic …, 2022 - ACS Publications
By incorporating photoreactive anthracene moieties into binuclear Dy2O2 motifs, we obtain
two new compounds with the formulas [Dy2 (SCN) 4 (L) 2 (dmpma) 4](1) and [Dy2 (SCN) 4 …

Mono- and Mixed Metal Complexes of Eu3+, Gd3+, and Tb3+ with a Diketone, Bearing Pyrazole Moiety and CHF2-Group: Structure, Color Tuning, and Kinetics of …

VE Gontcharenko, MA Kiskin, VD Dolzhenko… - Molecules, 2021 - mdpi.com
Three novel lanthanide complexes with the ligand 4, 4-difluoro-1-(1, 5-dimethyl-1H-pyrazol-
4-yl) butane-1, 3-dione (HL), namely [LnL3 (H2O) 2], Ln= Eu, Gd and Tb, were synthesized …

Single-molecule magnets within polyoxometalate-based frameworks

MB Zarch, M Mirzaei, M Bazargan, SK Gupta… - Dalton …, 2021 - pubs.rsc.org
As an extension of our interest in polyoxometalates (POMs) and lanthanoids, we report the
design and synthesis of two polyoxometalate-based frameworks under hydrothermal …

Donor radii in rare-earth complexes

C Harriswangler, JC Frías, MT Albelda… - Inorganic …, 2023 - ACS Publications
We present a set of donor radii for the rare-earth cations obtained from the analysis of
structural data available in the Cambridge Structural Database (CSD). Theoretical …