Facing and overcoming sensitivity challenges in biomolecular NMR spectroscopy

JH Ardenkjaer‐Larsen, GS Boebinger… - Angewandte Chemie …, 2015 - Wiley Online Library
In the Spring of 2013, NMR spectroscopists convened at the Weizmann Institute in Israel to
brainstorm on approaches to improve the sensitivity of NMR experiments, particularly when …

Tumor imaging using hyperpolarized 13C magnetic resonance spectroscopy

KM Brindle, SE Bohndiek, FA Gallagher… - Magnetic resonance …, 2011 - Wiley Online Library
Dynamic nuclear polarization is an emerging technique for increasing the sensitivity of
magnetic resonance imaging and spectroscopy, particularly for low‐γ nuclei. The technique …

[HTML][HTML] Deuterium metabolic imaging in the human brain at 9.4 Tesla with high spatial and temporal resolution

L Ruhm, N Avdievich, T Ziegs, AM Nagel… - Neuroimage, 2021 - Elsevier
Purpose To present first highly spatially resolved deuterium metabolic imaging (DMI)
measurements of the human brain acquired with a dedicated coil design and a fast chemical …

Accelerated MR spectroscopic imaging—a review of current and emerging techniques

W Bogner, R Otazo, A Henning - NMR in Biomedicine, 2021 - Wiley Online Library
Over more than 30 years in vivo MR spectroscopic imaging (MRSI) has undergone an
enormous evolution from theoretical concepts in the early 1980s to the robust imaging …

Hyperpolarized magnetic resonance as a sensitive detector of metabolic function

A Comment, ME Merritt - Biochemistry, 2014 - ACS Publications
Hyperpolarized magnetic resonance allows for noninvasive measurements of biochemical
reactions in vivo. Although this technique provides a unique tool for assaying enzymatic …

Fast dynamic 3D MR spectroscopic imaging with compressed sensing and multiband excitation pulses for hyperpolarized 13C studies

PEZ Larson, S Hu, M Lustig, AB Kerr… - Magnetic resonance …, 2011 - Wiley Online Library
Hyperpolarized 13C MR spectroscopic imaging can detect not only the uptake of the pre‐
polarized molecule but also its metabolic products in vivo, thus providing a powerful new …

Hyperpolarized 13C dehydroascorbate as an endogenous redox sensor for in vivo metabolic imaging

KR Keshari, J Kurhanewicz, R Bok… - Proceedings of the …, 2011 - National Acad Sciences
Reduction and oxidation (redox) chemistry is involved in both normal and abnormal cellular
function, in processes as diverse as circadian rhythms and neurotransmission. Intracellular …

A hyperpolarized equilibrium for magnetic resonance

JB Hövener, N Schwaderlapp, T Lickert… - Nature …, 2013 - nature.com
Nuclear magnetic resonance spectroscopy and imaging (MRI) play an indispensable role in
science and healthcare but use only a tiny fraction of their potential. No more than≈ 10 ppm …

3D compressed sensing for highly accelerated hyperpolarized 13C MRSI with in vivo applications to transgenic mouse models of cancer

S Hu, M Lustig, A Balakrishnan… - … in Medicine: An …, 2010 - Wiley Online Library
High polarization of nuclear spins in liquid state through hyperpolarized technology utilizing
dynamic nuclear polarization has enabled the direct monitoring of 13C metabolites in vivo at …

Hyperpolarized 13C metabolic imaging using dissolution dynamic nuclear polarization

RE Hurd, YF Yen, A Chen… - Journal of Magnetic …, 2012 - Wiley Online Library
This article describes the basic physics of dissolution dynamic nuclear polarization
(dissolution‐DNP), and the impact of the resulting highly nonequilibrium spin states, on the …