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Nickel–carbon bond oxygenation with green oxidants via high-valent nickel species
Described herein is the synthesis of the NiII complex (t BuMe2tacn) NiII (cycloneophyl)(t
BuMe2tacn= 1-tert-butyl-4, 7-dimethyl-1, 4, 7-triazacyclononane, cycloneophyl=− CH2CMe2 …
BuMe2tacn= 1-tert-butyl-4, 7-dimethyl-1, 4, 7-triazacyclononane, cycloneophyl=− CH2CMe2 …
C–H bond activation via concerted metalation–deprotonation at a palladium (iii) center
Herein we report the direct observation of C–H bond activation at an isolated mononuclear
Pd (III) center. The oxidation of the Pd (II) complex (MeN4) PdII (neophyl) Cl (neophyl …
Pd (III) center. The oxidation of the Pd (II) complex (MeN4) PdII (neophyl) Cl (neophyl …
Systematic Electronic Tuning on the Property and Reactivity of Cobalt–(Hydro) peroxo Intermediates
A series of cobalt (III)–peroxo complexes,[CoIII (R2-TBDAP)(O2)]+(1 R2; R2= Cl, H, and
OMe), and cobalt (III)–hydroperoxo complexes,[CoIII (R2-TBDAP)(O2H)(CH3CN)] 2+(2 R2) …
OMe), and cobalt (III)–hydroperoxo complexes,[CoIII (R2-TBDAP)(O2H)(CH3CN)] 2+(2 R2) …
Photoexcited Pd (II) auxiliaries enable light-induced control in C (sp 3)–H bond functionalisation
Herein we report the photophysical and photochemical properties of palladacycle
complexes derived from 8-aminoquinoline ligands, commonly used auxiliaries in C–H …
complexes derived from 8-aminoquinoline ligands, commonly used auxiliaries in C–H …
Csp 3–H bond activation mediated by a Pd (ii) complex under mild conditions
In this work, we disclose a new pentadentate pyridinophane ligand, N-methyl-N′-(2-
methylpyryl)-2, 11-diaza [3.3](2, 6) pyridinophane (PicCH3N4), and its Pd (II) complexes …
methylpyryl)-2, 11-diaza [3.3](2, 6) pyridinophane (PicCH3N4), and its Pd (II) complexes …
Stable M(II)-Radicals and Nickel(III) Complexes of a Bis(phenol) N-Heterocyclic Carbene Chelated to Group 10 Metal Ions
R Kunert, C Philouze, O Jarjayes, F Thomas - Inorganic Chemistry, 2019 - ACS Publications
The tetradentate ligand based on (1-imidazolium-3, 5-di tert-butylphenol) units was
prepared and chelated to group 10 metal ions (Ni (II), Pd (II), and Pt (II)), affording complexes …
prepared and chelated to group 10 metal ions (Ni (II), Pd (II), and Pt (II)), affording complexes …
Controlling Reactivity through Spin Manipulation: Steric Bulkiness of Peroxocobalt (III) Complexes
The intrinsic relationship between spin states and reactivity in peroxocobalt (III) complexes
was investigated, specifically focusing on the influence of steric modulation on supporting …
was investigated, specifically focusing on the influence of steric modulation on supporting …
Palladium K-edge X-ray Absorption Spectroscopy Studies on Controlled Ligand Systems
LP Westawker, JK Khusnutdinova, RF Wallick… - Inorganic …, 2023 - ACS Publications
X-ray absorption spectroscopy (XAS) is widely used across the life and physical sciences to
identify the electronic properties and structure surrounding a specific element. XAS is less …
identify the electronic properties and structure surrounding a specific element. XAS is less …
Mechanistic Insight into Palladium/Brønsted Acid Catalyzed Methoxycarbonylation and Hydromethoxylation of Internal Alkene: A Computational Study
L Han, K Lv, T Wang, Z Meng, J Zhang… - Inorganic Chemistry, 2023 - ACS Publications
Density functional theory (DFT) calculations were performed to study the palladium/Brønsted
acid-catalyzed methoxycarbonylation and hydromethoxylation reactions of internal alkene …
acid-catalyzed methoxycarbonylation and hydromethoxylation reactions of internal alkene …
Improved Oxidative C–C Bond Formation Reactivity of High-Valent Pd Complexes Supported by a Pseudo-Tridentate Ligand
There is a large interest in develo** oxidative transformations catalyzed by palladium
complexes that employ environmentally friendly and economical oxidizing reagents such as …
complexes that employ environmentally friendly and economical oxidizing reagents such as …