The replacement of one or more pyrrolic building block (s) of a porphyrin by a nonpyrrolic
heterocycle leads to the formation of so-called pyrrole-modified porphyrins (PMPs) …

This Review outlines the progress in the field of synthetic expanded carbaporphyrinoids.
The evolution of this topic is demonstrated with expanded porphyrin‐inspired systems with a …

Due to enthralling applications in various fields and augmenting fundamental wisdom, π-
conjugated macrocycles in general and porphyrin systems in particular are constantly …

Expanded porphyrins represent emerging structures in realizing topological chirality;
however, their inherent flexibility has hampered the effective chiral resolution. Herein, we …

Rhodium complexes of biphenylcorrole are reported, and the molecular structures of the
complexes are unambiguously confirmed by single-crystal X-ray analysis. The adj-CCNN …

The highly conjugated tetrapyrrolic porphyrin macrocycle and its contracted and expanded
congeners have been extensively used for a wide range of applications across diverse …

A pair of meso‐unsubstituted expanded carbaporphyrins containing two carbazole moieties
were prepared in high isolated yields (82 and 76%, respectively). The two macrocycles …

Isosmaragdyrin with an N3C2 core is successfully achieved by introducing a 2, 6-di-m-
phenylpyridine unit. The core is utilized to stabilize the Rh (I) ion in the N–Rh (I)–N bonding …

Two novel macrocycles, di (p‐benzi) decaphyrin and di (9, 10‐anthracenyl) decaphyrin have
been synthesized by condensing appropriate p‐phenylene based pentapyrrane or 9, 10 …

An unprecedented formation of a meso-fused β–β′ carbaporphyrin dimer and its monomer
with a keto group was described. These analogues were synthesized from carbatriphyrin …