Metal‐organic frameworks (MOFs) provide uniquely tunable, periodic platforms for site‐
isolation of reactive low‐valent metal complexes of relevance in modern catalysis …

Structural insight into reactive species can be achieved via strategies such as matrix
isolation in frozen glasses, whereby species are kinetically trapped, or by confinement within …

Numerous studies have focused on the mechanical control of solid structures and phase
changes in molecular crystals. However, the molecular-level understanding of how …

Metal–organic frameworks have developed into a formidable heterogeneous catalysis
platform in recent years. It is well established that thermolysis of coordinated solvents from …

The present review focuses on the solid state structural transformations in discrete
molecules. Since the molecules in the crystal lattice are closely packed, any transformation …

We report a novel approach toward the catalytic hydrogenation of CO2 to methanol
performed in the gas–solid phase using multinuclear iridium complexes at low temperature …

Reaction of the pincer-type ligand L3 supported complex [L3PbBr][BArF24](1) with Li [(C (═
N2) TMS)] furnishes [L3Pb (C (═ N2) TMS)][BArF24](2). Diazo-compound 2 eliminates …

Porous materials capable of hosting external molecules are paramount in basic and applied
research. Nonporous materials able to incorporate molecules via internal lattice …

Most nanoporous materials with molecular-scale pores are composed of directional covalent
or coordination bonds, such as porous metal–organic frameworks and organic network …

Living systems carry out the reduction of N2 to ammonia (NH3) through a series of
protonation and electron transfer steps under ambient conditions using the enzyme …