Recent advances in the design of magnetic molecules for use as cryogenic magnetic coolants

JL Liu, YC Chen, FS Guo, ML Tong - Coordination Chemistry Reviews, 2014 - Elsevier
This review outlines recent advances in the design of 3d-, 4f-, and 3d–4f type magnetic
molecules for use as excellent cryogenic magnetic coolants based on the magnetocaloric …

[HTML][HTML] Electronic structure and magnetic anisotropy design of functional metal complexes

A Raza, M Perfetti - Coordination Chemistry Reviews, 2023 - Elsevier
Chemical guidelines to target a well-defined electronic structure and magnetic anisotropy
are of primary importance in physics, chemistry and biology. Our literature overview …

Coordination‐Cluster‐Based Molecular Magnetic Refrigerants

S Zhang, P Cheng - The Chemical Record, 2016 - Wiley Online Library
Coordination polymers serving as molecular magnetic refrigerants have been attracting
great interest. In particular, coordination cluster compounds that demonstrate their apparent …

Two Isostructural 3D Lanthanide Coordination Networks (Ln = Gd3+, Dy3+) with Squashed Cuboid-Type Nanoscopic Cages Showing Significant Cryogenic …

S Biswas, HS Jena, A Adhikary, S Konar - Inorganic Chemistry, 2014 - ACS Publications
Two isostructural lanthanide-based 3D coordination networks [Ln= Gd3+ (1), Dy3+ (2)] with
densely packed distorted cuboid nanoscopic cages are reported for the first time. Magnetic …

Single‐Molecule Magnetism, Enhanced Magnetocaloric Effect, and Toroidal Magnetic Moments in a Family of Ln4 Squares

C Das, S Vaidya, T Gupta, JM Frost… - … A European Journal, 2015 - Wiley Online Library
Abstract Three cationic [Ln4] squares (Ln= lanthanide) were isolated as single crystals and
their structures solved as [Dy4 (μ4‐OH)(HL)(H2L) 3 (H2O) 4] Cl2⋅(CH3OH) 4⋅(H2O) 8 …

Synthesis and Characterization of Two Lanthanide (Gd3+ and Dy3+)-Based Three-Dimensional Metal Organic Frameworks with Squashed Metallomacrocycle Type …

S Biswas, HS Jena, S Goswami, S Sanda… - Crystal growth & …, 2014 - ACS Publications
Two novel isostructural lanthanide-based three-dimensional (3D) metal organic frameworks
(MOFs),[Ln2 (pam) 3 (DMF) 2 (H2O) 2] n· n DMF {Ln= Gd (1), Dy (2); H2pam= 4, 4 …

Fluoride‐Bridged {GdIII3MIII2} (M=Cr, Fe, Ga) Molecular Magnetic Refrigerants

KS Pedersen, G Lorusso, JJ Morales… - Angewandte Chemie …, 2014 - Wiley Online Library
The reaction of fac‐[MIIIF3 (Me3tacn)]⋅ x H2O with Gd (NO3) 3⋅ 5H2O affords a series of
fluoride‐bridged, trigonal bipyramidal {GdIII3MIII2}(M= Cr (1), Fe (2), Ga (3)) complexes …

Three-dimensional two-fold interpenetrated Cr III–Gd III heterometallic framework as an attractive cryogenic magnetorefrigerant

SJ Liu, XR **e, TF Zheng, J Bao, JS Liao, JL Chen… - …, 2015 - pubs.rsc.org
The hydrothermal reaction of CrO3, Gd2O3 and iminodiacetic acid (H2IDA) yields a three-
dimensional (3D) two-fold interpenetrated complex [CrGd (IDA) 2 (C2O4)]∞(1). The oxalate …

Observation of a large magnetocaloric effect in a 2D Gd (III)-based coordination polymer

S Biswas, A Adhikary, S Goswami, S Konar - Dalton Transactions, 2013 - pubs.rsc.org
Observation of a large magnetocaloric effect in a 2D Gd( iii )-based coordination polymer -
Dalton Transactions (RSC Publishing) DOI:10.1039/C3DT51668G Royal Society of …

Switching of the Magnetocaloric Effect of MnII Glycolate by Water Molecules

YC Chen, FS Guo, JL Liu, JD Leng… - … A European Journal, 2014 - Wiley Online Library
The transformation of MnII glycolates (glc) between the three‐dimensional coordination
polymer [Mn (glc) 2] n (1) and discrete mononuclear phase [Mn (glc) 2 (H2O) 2](2) can be …