Since the definition of the “12 Principles of Green Chemistry” more than 20 years ago,
chemists have become increasingly mindful of the need to conserve natural resources and …

Very recently, directing group (DG) migration has emerged as a practical strategy for
transition-metal-catalysed direct C–H activation, resulting in a highly atom-economical …

Axially chiral open‐chain olefins represent an underexplored class of chiral platform. In this
report, two classes of tetrasubstituted axially chiral acyclic olefins have been accessed in …

Detailed density functional theory calculations provide valuable insight into reactivity-
controlling factors in transition metal-catalyzed C–H activation by carboxylate assistance …

Metal-catalyzed activations of inert sp2C–H and sp3C–H bonds have recently brought about
a revolution in the synthesis of useful molecules and molecular materials. Among them, the …

Herein, we report the additive-controlled divergent synthesis of tetrasubstituted 1, 3-enynes
and alkynylated 3 H-pyrrolo [1, 2-a] indol-3-ones through rhodium-catalyzed C–H …

Transition metal-controlled divergent annulation reactions of azomethine imines with
iodonium ylides via C-centered [1, 2]-rearrangement have been developed. The azomethine …

Exploring multistep cascade reactions triggered by C–H activation are recognized as
appealing, yet challenging. Herein, we disclose a Rh (III)-catalyzed domino C–H coupling of …

C–H activation provides a straightforward approach to construct new chemical bonds and
privileged heterocycles. However, due to common deficiencies, C–H activation still faces a …

Co (III)-catalyzed highly regio-and stereoselective direct C6 olefination of 2-pyridones with
alkynes has been developed with the assistance of chelation. Upon variation of the reaction …