Self‐healing in supramolecular polymers

A Campanella, D Döhler… - Macromolecular rapid …, 2018 - Wiley Online Library
Adaption and self‐healing are two major principles in material science, often coupled with
the placement of supramolecular moieties within a material. Proper molecular design can …

Dynamic ordering and phase segregation in hydrogen-bonded polymers

S Chen, WH Binder - Accounts of Chemical Research, 2016 - ACS Publications
Conspectus Hydrogen bonds (H-bonds) constitute highly relevant structural units of
molecular self-assembly. They bridge biological and synthetic sciences, implementing …

50th anniversary perspective: Networks and gels: Soft but dynamic and tough

C Creton - Macromolecules, 2017 - ACS Publications
Soft polymer networks have seen an explosion of recent developments motivated by new
high tech applications in the biomedical field or in engineering. We present a candid and …

Templated PISA: Driving Polymerization‐Induced Self‐Assembly towards Fibre Morphology

G Mellot, JM Guigner, L Bouteiller… - Angewandte …, 2019 - Wiley Online Library
Dispersions of block copolymer fibres in water have many potential applications and can be
obtained by polymerization‐induced self‐assembly (PISA), but only under very restricted …

Tuning the self-healing response of poly (dimethylsiloxane)-based elastomers

D Döhler, J Kang, CB Cooper, JBH Tok… - ACS Applied Polymer …, 2020 - ACS Publications
We present a comprehensive investigation of mechanical properties of supramolecular
polymer networks with rationally developed multistrength hydrogen-bonding interactions …

The challenges of obtaining mechanical strength in self-healing polymers containing dynamic covalent bonds

S Nevejans, N Ballard, M Fernández, B Reck… - Polymer, 2019 - Elsevier
Although the use of dynamic bonds for the development of self-healing polymers has been
widely studied, their concomitant influence on the mechanical properties and the …

Dynamics of entangled linear supramolecular chains with sticky side groups: Influence of hindered fluctuations

M Ahmadi, LGD Hawke, H Goldansaz… - …, 2015 - ACS Publications
The design and effective application of supramolecular transient polymer networks based on
the assembly of entangled polymer building blocks requires not only precise description of …

Effect of the dianhydride/branched diamine ratio on the architecture and room temperature healing behavior of polyetherimides

A Susa, RK Bose, AM Grande… - … applied materials & …, 2016 - ACS Publications
Traditional polyetherimides (PEIs) are commonly synthesized from an aromatic diamine and
an aromatic dianhydride (eg, 3, 4′-oxidianiline (ODA) and 4, 4′-oxidiphtalic anhydride …

A critical approach to polymer dynamics in supramolecular polymers

M Golkaram, K Loos - Macromolecules, 2019 - ACS Publications
Over the past few years, the concurrent (1) development of polymer synthesis and (2)
introduction of new mathematical models for polymer dynamics have evolved the classical …

A combined fracture mechanical–rheological study to separate the contributions of hydrogen bonds and disulphide linkages to the healing of poly (urea-urethane) …

AM Grande, JC Bijleveld, SJ Garcia, S Van Der Zwaag - Polymer, 2016 - Elsevier
This work presents a detailed study into the rheological properties and fracture healing
behaviour of two poly (urea-urethane) polymers containing (i) hydrogen bonds and (ii) …