Advances in the synthesis of preceramic polymers for the formation of silicon-based and ultrahigh-temperature non-oxide ceramics

BJ Ackley, KL Martin, TS Key, CM Clarkson… - Chemical …, 2023 - ACS Publications
Preceramic polymers (PCPs) are a group of specialty macromolecules that serve as
precursors for generating inorganics, including ceramic carbides, nitrides, and borides …

Remarkable gas separation performance of a thermally rearranged membrane derived from an alkynyl self-crosslinkable precursor

S Zhang, Z Xu, Y Weng, M Cai, Y Wang, W Zhu… - Journal of Membrane …, 2023 - Elsevier
One critical problem confronted with gas separation industrial is membrane with high
permeability, selectivity, mechanical strong and reliability. Here, we reported a high …

Assessing pyrolysis behavior of silicon-containing arylacetylene resin via experiments and ReaxFF MD simulations

F Zheng, K Wan, F Huang, B Niu, Y Shi, D Wei… - Journal of Analytical and …, 2022 - Elsevier
Silicon-containing arylacetylene resin (PSA), a thermosetting organic-inorganic hybrid resin
of high heat-resistance performs well in ablation process, whereas its pyrolysis behavior …

Perfluorocyclobutyl aryl ether-based poly (silylene arylacetylene) s with a low dielectric constant for advanced wave-transparent composites

C Gong, X Huang, J Li, S Lv, Y Zhou, J Tang… - European Polymer …, 2022 - Elsevier
A high-performance matrix with good mechanical properties, low dielectric constant as well
as high thermal stability for advanced composites is in demand for the aerospace industry. In …

Thermostable SiCO@ BN sheets with enhanced electromagnetic wave absorption

Y Hou, W Yang, C Zhong, S Wu, Y Wu, F Liu… - Chemical Engineering …, 2019 - Elsevier
Due to the extremely low transmission loss, hexagonal boron nitride (h-BN) is always used
as a permeable material for electromagnetic wave (EMW). However, an excellent …

Thermally cross-linked alkynyl-based polyimide membranes for efficient helium separation and physical aging control

H Ma, H Liu, F Tian, B Gao, L Liang, Y Liu… - Chemical Engineering …, 2024 - Elsevier
Membrane separation technology plays a critical role in the utilization of helium (He)
resources. Yet, the performance of current polymer membranes is hindered by a trade-off …

Design of Co‐Cured Multi‐Component Thermosets with Enhanced Heat Resistance, Toughness, and Processability via a Machine Learning Approach

S Song, X Xu, H Lan, L Gao, J Lin… - Macromolecular Rapid …, 2024 - Wiley Online Library
Designing heat‐resistant thermosets with excellent comprehensive performance has been a
long‐standing challenge. Co‐curing of various high‐performance thermosets is an effective …

Synthesis and characterization of poly (dimethylsilylene ethynylenephenyleneethynylene) terminated with phenylacetylene

F Wang, J Zhang, J Huang, H Yan, F Huang, L Du - Polymer Bulletin, 2006 - Springer
A novel easily processable resin, poly (dimethylsilylene ethynylenephenyleneethynylene)[-
Si (CH 3) 2-C≡ CC 6 H 4-C≡ C-] n terminated with phenylacetylene, was developed. And …

Thermal curing and degradation behaviour of silicon-containing arylacetylene resins

K Guo, P Li, Y Zhu, F Wang, H Qi - Polymer Degradation and Stability, 2016 - Elsevier
Silicon-containing aryacetylene resins (PSAs) have already shown potential application as
heat-resistant materials due to their excellent thermal stability. The formation and …

Elucidation of Organic Reaction Mechanisms Using Nuclear Magnetic Resonance: A review

J Carreras, M Caputo, D Colasurdo, M Pila, D Ruiz… - Appl. Magn. Reson …, 2024 - Springer
Nuclear magnetic resonance (NMR), a technique mainly used for structure determination,
has also been extensively used for mechanism elucidation. The study of the different steps …