Recent Advances in Alkenyl sp2 C–H and C–F Bond Functionalizations: Scope, Mechanism, and Applications
MZ Lu, J Goh, M Maraswami, Z Jia, JS Tian… - Chemical …, 2022 - ACS Publications
Alkenes and their derivatives are featured widely in a variety of natural products,
pharmaceuticals, and advanced materials. Significant efforts have been made toward the …
pharmaceuticals, and advanced materials. Significant efforts have been made toward the …
Pyrrole: a resourceful small molecule in key medicinal hetero-aromatics
Pyrrole is widely known as a biologically active scaffold which possesses a diverse nature of
activities. The combination of different pharmacophores in a pyrrole ring system has led to …
activities. The combination of different pharmacophores in a pyrrole ring system has led to …
Recent advances in transition metal-free annulation toward heterocycle diversity based on the C–N bond cleavage of enaminone platform
XY Chen, X Zhang, JP Wan - Organic & Biomolecular Chemistry, 2022 - pubs.rsc.org
Enaminones and analogous stable enamines are well known as platform building blocks in
organic synthesis for the construction of heterocyclic compounds, especially N-heterocycles …
organic synthesis for the construction of heterocyclic compounds, especially N-heterocycles …
Formal [4+ 1] annulation reactions in the synthesis of carbocyclic and heterocyclic systems
JR Chen, XQ Hu, LQ Lu, WJ **ao - Chemical reviews, 2015 - ACS Publications
The development of new strategies and chemical reactions continues to be a major focus of
research efforts in the modern synthetic organic community. 1 Of the various types of …
research efforts in the modern synthetic organic community. 1 Of the various types of …
An insight into the advanced synthetic recipes to access ubiquitous indole heterocycles
Indoles are amongst the most essential class of heteroaromatics in organic chemistry, being
commonly found in biologically active natural products. Indole and its derivatives have …
commonly found in biologically active natural products. Indole and its derivatives have …
Rhodium‐Catalyzed C H Annulation of Nitrones with Alkynes: A Regiospecific Route to Unsymmetrical 2, 3‐Diaryl‐Substituted Indoles
H Yan, H Wang, X Li, X **n, C Wang… - Angewandte …, 2015 - Wiley Online Library
Abstract The direct C H annulation of anilines or related compounds with internal alkynes
provides straightforward access to 2, 3‐disubstituted indole products. However, this …
provides straightforward access to 2, 3‐disubstituted indole products. However, this …
Regiocontrolled synthesis of polysubstituted pyrroles starting from terminal alkynes, sulfonyl azides, and allenes
T Miura, K Hiraga, T Biyajima, T Nakamuro… - Organic …, 2013 - ACS Publications
1-Sulfonyl-1, 2, 3-triazoles, readily prepared from terminal alkynes and sulfonyl azides, react
with allenes in the presence of a nickel (0) catalyst to produce the corresponding …
with allenes in the presence of a nickel (0) catalyst to produce the corresponding …
Recent developments in the synthesis of nitrogen-containing heterocycles from β-aminovinyl esters/ketones as C [double bond, length as m-dash] C–N donors
XF **a, YN Niu - Organic & Biomolecular Chemistry, 2022 - pubs.rsc.org
Nitrogen-containing heterocycles are ubiquitous fragments of numerous natural products,
pharmaceuticals, designed bioactive drug candidates and agrochemicals. During the past …
pharmaceuticals, designed bioactive drug candidates and agrochemicals. During the past …
Synthesis of Pyrroles from Terminal Alkynes, N-Sulfonyl Azides, and Alkenyl Alkyl Ethers through 1-Sulfonyl-1,2,3-triazoles
A method for synthesis of substituted pyrroles has been developed. 1-Sulfonyl-1, 2, 3-
triazoles generated from terminal alkynes gave α-imino rhodium carbene complexes, which …
triazoles generated from terminal alkynes gave α-imino rhodium carbene complexes, which …
Synthesis of diverse pentasubstituted pyrroles by a gold (I)-catalyzed cascade rearrangement-cyclization of tertiary enamide
W Li, R Shi, S Chen, X Zhang, W Peng… - The Journal of …, 2022 - ACS Publications
An efficient Au (I)-catalyzed intramolecular cascade reaction of tertiary enamides tethered an
alkynyl group has been developed. The process is composed of a propargyl-claisen …
alkynyl group has been developed. The process is composed of a propargyl-claisen …