Bimetallic sites for catalysis: from binuclear metal sites to bimetallic nanoclusters and nanoparticles

L Liu, A Corma - Chemical Reviews, 2023 - ACS Publications
Heterogeneous bimetallic catalysts have broad applications in industrial processes, but
achieving a fundamental understanding on the nature of the active sites in bimetallic …

Chemical reactivity under nanoconfinement

AB Grommet, M Feller, R Klajn - Nature nanotechnology, 2020 - nature.com
Confining molecules can fundamentally change their chemical and physical properties.
Confinement effects are considered instrumental at various stages of the origins of life, and …

Direct conversion of methane with O2 at room temperature over edge-rich MoS2

J Mao, H Liu, X Cui, Y Zhang, X Meng, Y Zheng… - Nature Catalysis, 2023 - nature.com
Conversion of methane to value-added chemicals at low temperature by directly using
inexpensive O2 as oxidant offers an ideal route for methane utilization but remains a great …

Confining isolated atoms and clusters in crystalline porous materials for catalysis

L Liu, A Corma - Nature Reviews Materials, 2021 - nature.com
Abstract Structure–reactivity relationships for nanoparticle-based catalysts have been
greatly influenced by the study of catalytic materials with either supported isolated metal …

Hydrophobic zeolite modification for in situ peroxide formation in methane oxidation to methanol

Z **, L Wang, E Zuidema, K Mondal, M Zhang… - Science, 2020 - science.org
Selective partial oxidation of methane to methanol suffers from low efficiency. Here, we
report a heterogeneous catalyst system for enhanced methanol productivity in methane …

Fischer–Tropsch synthesis to olefins boosted by MFI zeolite nanosheets

C Wang, W Fang, Z Liu, L Wang, Z Liao, Y Yang… - Nature …, 2022 - nature.com
Catalytic reactions are severely restricted by the strong adsorption of product molecules on
the catalyst surface, where promoting desorption of the product and hindering its re …

Triple ionic–electronic conducting oxides for next-generation electrochemical devices

M Papac, V Stevanović, A Zakutayev, R O'Hayre - Nature materials, 2021 - nature.com
Triple ionic–electronic conductors (TIECs) are materials that can simultaneously transport
electronic species alongside two ionic species. The recent emergence of TIECs provides …

An electrochemical haber-bosch process

V Kyriakou, I Garagounis, A Vourros, E Vasileiou… - Joule, 2020 - cell.com
Ammonia, produced via the Haber-Bosch (HB) process, is globally the leading chemical in
energy consumption and carbon dioxide emissions. In ammonia plants, hydrogen is …

Sustainable production of benzene from lignin

Q Meng, J Yan, R Wu, H Liu, Y Sun, NN Wu… - Nature …, 2021 - nature.com
Benzene is a widely used commodity chemical, which is currently produced from fossil
resources. Lignin, a waste from lignocellulosic biomass industry, is the most abundant …

Applications of zeolites to C1 chemistry: recent advances, challenges, and opportunities

Q Zhang, J Yu, A Corma - Advanced Materials, 2020 - Wiley Online Library
C1 chemistry, which is the catalytic transformation of C1 molecules including CO, CO2, CH4,
CH3OH, and HCOOH, plays an important role in providing energy and chemical supplies …