Design of the synergistic rectifying interfaces in Mott–Schottky catalysts

D Xu, SN Zhang, JS Chen, XH Li - Chemical Reviews, 2022 - ACS Publications
The functions of interfacial synergy in heterojunction catalysts are diverse and powerful,
providing a route to solve many difficulties in energy conversion and organic synthesis …

Strong metal–support interaction in heterogeneous catalysts

Z Luo, G Zhao, H Pan, W Sun - Advanced Energy Materials, 2022 - Wiley Online Library
Strong metal–support interaction (SMSI) in supported metal catalysts, typically accompanied
by the formation of encapsulation layers over metal nanoparticles, has drawn intense …

Understanding the structure-performance relationship of active sites at atomic scale

R Li, D Wang - Nano Research, 2022 - Springer
Metal-based atomically dispersed catalysts have attracted more attention because of their
excellent catalytic performance and nearly 100% atom utilization. Therefore, it is very …

Dynamic interplay between metal nanoparticles and oxide support under redox conditions

H Frey, A Beck, X Huang, JA van Bokhoven… - Science, 2022 - science.org
The dynamic interactions between noble metal particles and reducible metal-oxide supports
can depend on redox reactions with ambient gases. Transmission electron microscopy …

Engineering heterogeneous catalysis with strong metal–support interactions: characterization, theory and manipulation

T Pu, W Zhang, M Zhu - Angewandte Chemie International …, 2023 - Wiley Online Library
Strong metal–support interactions (SMSI) represent a classic yet fast‐growing area in
catalysis research. The SMSI phenomenon results in the encapsulation and stabilization of …

Induced activation of the commercial Cu/ZnO/Al2O3 catalyst for the steam reforming of methanol

D Li, F Xu, X Tang, S Dai, T Pu, X Liu, P Tian, F Xuan… - Nature Catalysis, 2022 - nature.com
The surface structure of heterogeneous catalysts is closely associated with their catalytic
performance. Current efforts for structural modification mainly focus on improving the catalyst …

Metal–support interactions in metal/oxide catalysts and oxide–metal interactions in oxide/metal inverse catalysts

Y Li, Y Zhang, K Qian, W Huang - ACS Catalysis, 2022 - ACS Publications
Solid catalysts usually consist of multicomponents, within which interfacial interactions have
been recognized as a key factor affecting structures and catalytic performance. Metal …

Overturning CO2 Hydrogenation Selectivity with High Activity via Reaction-Induced Strong Metal–Support Interactions

H **n, L Lin, R Li, D Li, T Song, R Mu… - Journal of the …, 2022 - ACS Publications
Encapsulation of metal nanoparticles by support-derived materials known as the classical
strong metal–support interaction (SMSI) often happens upon thermal treatment of supported …

Polystyrene waste thermochemical hydrogenation to ethylbenzene by a N-bridged Co, Ni dual-atom catalyst

R Li, Z Zhang, X Liang, J Shen, J Wang… - Journal of the …, 2023 - ACS Publications
Recycling waste plastics requires the degradation of plastics into small molecules. However,
various products are widely distributed using traditional methods of depolymerizing …

Interfacial compatibility critically controls Ru/TiO2 metal-support interaction modes in CO2 hydrogenation

J Zhou, Z Gao, G **ang, T Zhai, Z Liu, W Zhao… - Nature …, 2022 - nature.com
Supports can widely affect or even dominate the catalytic activity, selectivity, and stability of
metal nanoparticles through various metal-support interactions (MSIs). However, underlying …