Multireference approaches for excited states of molecules

H Lischka, D Nachtigallova, AJA Aquino… - Chemical …, 2018 - ACS Publications
Understanding the properties of electronically excited states is a challenging task that
becomes increasingly important for numerous applications in chemistry, molecular physics …

Ultraviolet Photodissociation of Proteinogenic Amino Acids

B Moore, K Mahoney, MF Zeng… - Journal of the …, 2023 - ACS Publications
The ultraviolet photochemistry of the amino acids glycine, leucine, proline, and serine in
their neutral forms was investigated using parahydrogen matrix-isolation spectroscopy …

Nonadiabatic decomposition of gas-phase RDX through conical intersections: an ONIOM-CASSCF study

A Bhattacharya, ER Bernstein - The Journal of Physical Chemistry …, 2011 - ACS Publications
Topographical exploration of nonadiabatically coupled ground-and excited-electronic-state
potential energy surfaces (PESs) of the isolated RDX molecule was performed using the …

Matrix-controlled photofragmentation of formamide: dynamics simulation in argon by nonadiabatic QM/MM method

M Eckert-Maksić, M Vazdar, M Ruckenbauer… - Physical Chemistry …, 2010 - pubs.rsc.org
The short-time photodynamics (2 ps) of formamide embedded into an Ar matrix starting from
the low-lying singlet excited S1 (n0π*) and S2 (ππ*) states were explored using a …

Experimental and theoretical study of the pyrrole cluster photochemistry: closing the πσ* dissociation pathway by complexation

V Poterya, V Profant, M Fárník, P Slavíček… - The Journal of chemical …, 2007 - pubs.aip.org
Photolysis of size selected pyrrole clusters has been investigated and compared to the
photolysis of an isolated pyrrole molecule. Experimentally, size distributions of different …

Role of Triplet States in the Photolysis of Proteogenic Amino Acids

C Guerra, YA Rodríguez‐Núñez… - …, 2024 - Wiley Online Library
This investigation delves into the UV photodissociation of pivotal amino acids (Alanine,
Glycine, Leucine, Proline, and Serine) at 213 nm, providing insights into triplet‐state …

Formic acid dimers in a nitrogen matrix

S Lopes, R Fausto, L Khriachtchev - The Journal of Chemical Physics, 2018 - pubs.aip.org
Formic acid (HCOOH) dimers are studied by infrared spectroscopy in a nitrogen matrix and
by ab initio calculations. We benefit from the use of a nitrogen matrix where the lifetime of the …

Impulsive UV-pump/X-ray probe study of vibrational dynamics in glycine

R Mincigrucci, M Kowalewski, JR Rouxel… - Scientific reports, 2018 - nature.com
We report an ab-initio study of a pump-probe experiment on the amino-acid glycine. We
consider an UV pump followed by an X-ray probe tuned to carbon K-edge and study the …

Conformation specific and charge directed reactivity of radical cation intermediates of α-substituted (amino, hydroxy, and keto) bioactive carboxylic acids

A Bhattacharya, JW Shin, KJ Clawson… - Physical Chemistry …, 2010 - pubs.rsc.org
The reactivity of radical cation carboxylic acids is investigated on the basis of mass
spectrometry, infrared-vacuum ultraviolet (IR-VUV) photoionization spectroscopy, and high …

Photostability and solvation: photodynamics of microsolvated zwitterionic glycine

M Ončák, H Lischka, P Slavíček - Physical Chemistry Chemical Physics, 2010 - pubs.rsc.org
Photoinduced processes of the zwitterionic glycine solvated with one and two water
molecules were investigated using both static (CASSCF, MRCI and EOM-CCSD methods) …