Beyond the Hofmeister series: Ion-specific effects on proteins and their biological functions

HI Okur, J Hladílková, KB Rembert, Y Cho… - The Journal of …, 2017 - ACS Publications
Ions differ in their ability to salt out proteins from solution as expressed in the lyotropic or
Hofmeister series of cations and anions. Since its first formulation in 1888, this series has …

Cononsolvency of thermoresponsive polymers: where we are now and where we are going

S Bharadwaj, BJ Niebuur, K Nothdurft, W Richtering… - Soft Matter, 2022 - pubs.rsc.org
Cononsolvency is an intriguing phenomenon where a polymer collapses in a mixture of
good solvents. This cosolvent-induced modulation of the polymer solubility has been …

Smart responsive polymers: Fundamentals and design principles

D Mukherji, CM Marques… - Annual Review of …, 2020 - annualreviews.org
In this review, we summarize recent theoretical and computational developments in the field
of smart responsive materials, together with complementary experimental data. A material is …

Phase Separation of Homopolymers in Binary Mixed Solvents─ The Co-Nonsolvency Effect

P Zhang - Macromolecules, 2024 - ACS Publications
As one of the most intriguing phenomena in polymer solutions, the co-nonsolvency effect
refers to the collapse of a homopolymer chain or phase separation of homopolymer …

Mechanism of polymer collapse in miscible good solvents

F Rodríguez-Ropero, T Hajari… - The Journal of Physical …, 2015 - ACS Publications
We propose a physical mechanism for co-nonsolvency of a stimulus-responsive polymer in
water/methanol mixed solution based on results obtained with molecular simulations. Even …

[HTML][HTML] Communication: Cosolvency and cononsolvency explained in terms of a Flory-Huggins type theory

J Dudowicz, KF Freed, JF Douglas - The Journal of chemical physics, 2015 - pubs.aip.org
Standard Flory-Huggins (FH) theory is utilized to describe the enigmatic cosolvency and
cononsolvency phenomena for systems of polymers dissolved in mixed solvents. In …

Cononsolvency effect: when the hydrogen bonding between a polymer and a cosolvent matters

H Yong, JU Sommer - Macromolecules, 2022 - ACS Publications
Despite the fact that the observation of cononsolvency was reported as early as four
decades ago, its phase-transition mechanism is still under debate. In this work, we provided …

Relating side chain organization of PNIPAm with its conformation in aqueous methanol

D Mukherji, M Wagner, MD Watson, S Winzen… - Soft Matter, 2016 - pubs.rsc.org
Combining nuclear magnetic resonance (NMR), dynamic light scattering (DLS), and μs long
all-atom simulations with two million particles, we establish a delicate correlation between …

[HTML][HTML] Switching (bio-) adhesion and friction in liquid by stimulus responsive polymer coatings

Y Yu, MB Pérez, C Cao, S de Beer - European Polymer Journal, 2021 - Elsevier
Controlling (bio-) adhesion and friction is essential in many bio-medical and industrial
applications. Such control can be achieved using stimulus responsive polymers. Coatings …

Adsorption–attraction model for co-nonsolvency in polymer brushes

JU Sommer - Macromolecules, 2017 - ACS Publications
We study the properties of a polymer brush exposed to a mixture of two solvents where one
component, called the co-nonsolvent (CNS), has a stronger preference with respect to the …