Molecule-like synthesis of ligand-protected metal nanoclusters

Q Yao, M Zhu, Z Yang, X Song, X Yuan… - Nature Reviews …, 2024 - nature.com
Ligand-protected metal nanoclusters (NCs) are ultrasmall particles (< 3 nm) that represent
the molecular state of metal materials. Owing to their molecule-like structure—particularly …

Molecular reactivity of thiolate-protected noble metal nanoclusters: synthesis, self-assembly, and applications

Q Yao, Z Wu, Z Liu, Y Lin, X Yuan, J **e - Chemical Science, 2021 - pubs.rsc.org
Thiolate-protected noble metal (eg, Au and Ag) nanoclusters (NCs) are ultra-small particles
with a core size of less than 3 nm. Due to the strong quantum confinement effects and …

Supercrystal engineering of atomically precise gold nanoparticles promoted by surface dynamics

Q Yao, L Liu, S Malola, M Ge, H Xu, Z Wu, T Chen… - Nature Chemistry, 2023 - nature.com
The controllable packing of functional nanoparticles (NPs) into crystalline lattices is of
interest in the development of NP-based materials. Here we demonstrate that the size …

Advances in Cu nanocluster catalyst design: Recent progress and promising applications

S Biswas, S Das, Y Negishi - Nanoscale Horizons, 2023 - pubs.rsc.org
The quest for cleaner pathways to the production of fuels and chemicals from non-fossil
feedstock, efficient transformation of raw materials to value-added chemicals under mild …

Self‐assembly of precision noble metal nanoclusters: hierarchical structural complexity, colloidal superstructures, and applications

JV Rival, P Mymoona, KM Lakshmi, Nonappa… - Small, 2021 - Wiley Online Library
Ligand protected noble metal nanoparticles are excellent building blocks for colloidal self‐
assembly. Metal nanoparticle self‐assembly offers routes for a wide range of multifunctional …

Atomically precise thiolate‐protected gold nanoclusters: Current status of designability of the structure and physicochemical properties

S Hossain, D Hirayama, A Ikeda, M Ishimi… - …, 2023 - Wiley Online Library
Thiolate (SR)‐protected gold nanoclusters (Aun (SR) m NCs) are a rare type of material
capable of simultaneously exhibiting multiple physicochemical properties well‐suited to …

Thiolate‐protected metal nanoclusters: Recent development in synthesis, understanding of reaction, and application in energy and environmental field

T Kawawaki, A Ebina, Y Hosokawa, S Ozaki, D Suzuki… - Small, 2021 - Wiley Online Library
Metal nanoclusters (NCs), which are composed of about 250 or fewer metal atoms, possess
great potential as novel functional materials. Fundamental research on metal NCs gradually …

Assembly-induced spin transfer and distance-dependent spin coupling in atomically precise AgCu nanoclusters

N **a, J **ng, D Peng, S Ji, J Zha, N Yan, Y Su… - Nature …, 2022 - nature.com
Nanoparticle assembly paves the way for unanticipated properties and applications from the
nanoscale to the macroscopic world. However, the study of such material systems is greatly …

Nanoarchitectonics for coordination asymmetry and related chemistry

K Ariga, M Shionoya - Bulletin of the Chemical Society of Japan, 2021 - academic.oup.com
Nanoarchitectonics is a concept envisioned to produce functional materials from nanoscale
units through fusion of nanotechnology with other scientific disciplines. For component …

Controlled colloidal metal nanoparticles and nanoclusters: recent applications as cocatalysts for improving photocatalytic water-splitting activity

T Kawawaki, Y Mori, K Wakamatsu, S Ozaki… - Journal of Materials …, 2020 - pubs.rsc.org
In recent years, research on the use of metal nanoparticles (NPs) and nanoclusters (NCs)
synthesized by liquid-phase reduction in water-splitting photocatalysts has been actively …