The most fundamental concepts in chemistry are structure, energetics, reactivity and their
inter-relationships, which are indispensable for promoting chemistry into a rational science …

Kinetic Isotope Effects in the Study of Organometallic Reaction Mechanisms | Chemical Reviews
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Surface organometallic chemistry is an area of heterogeneous catalysis which has recently
emerged as a result of a comparative analysis of homogeneous and heterogeneous …

This study reports the highly selective (more than 95%) dehydrogenation of propane to
propylene as well as the reverse hydrogenation reaction by silica-supported single-site Zn …

The title topic is reviewed with emphasis on catalysis and on recent advances. Alkane σ
complexes, Shilov chemistry and oxidative addition routes are covered. Attention is also …

Though often perceived as the simple metaphorical hybrid of synthetic inorganic and
organic chemistry, synthetic organometallic chemistry continues to vigorously differentiate …

A series of studies have been conducted by experimental and theoretical methods on the
synthesis, structures, and reactions of Cp* Rh boryl complexes that are likely intermediates …

C− H bond activations of benzene and methane by M (η 2-O2CH) 2 (M= Pd or Pt) are
theoretically investigated with density functional theory (DFT), MP2-MP4 (SDQ), and CCSD …

In this Forum Article, we discuss the use of redox-active pincer-type ligands to enable
multielectron reactivity, specifically nitrene group transfer, at the electron-poor metals …

Turning a disadvantage to an advantage: The rather disappointing reactivity of the metal–
nitrogen bond in comparison to the metal–carbon bond resulted in the neglect of …