Nitric oxide (NO) is an important signaling molecule that is involved in a wide range of
physiological and pathological events in biology. Metal coordination chemistry, especially …

Nonplanar distortions of tetrapyrroles are prevalent in the hemes of hemoproteins, the
pigments of photosynthetic proteins, and cofactor F430 of methylreductase. The nonplanarity …

The development, characterization, and technological exploitation of new materials,
particularly as components in 'smart'systems, are key challenges for chemistry and physics …

Over the past few years extensive studies of model hemes have been carried out that are
aimed at understanding the effect of axial ligands and porphyrin substituents on the …

Models of the Bis-Histidine-Ligated Electron-Transferring Cytochromes. Comparative Geometric
and Electronic Structure of Low-Spin Ferro- and Ferrihemes | Chemical Reviews Recently …

Reaction of cis-[FeIII (cyclam) Cl2] Cl in acidic H2O/CH3OH or CH3CN/H2O mixtures with
NaN3 at 50° C produced upon addition of NaClO4 or NaPF6 the complex trans-[FeIII …

This review describes the effects of highly deformed porphyrin ring on the electronic
structures of iron (III) porphyrinates, which includes (i) the electron configurations in low-spin …

The nitrophorins are NO-carrying heme proteins that are found in the saliva of two species of
blood-sucking insects, the kissing bug (Rhodnius prolixus) and the bedbug (Cimex …

To examine the influence of mixed substituents on the structural, electrochemical redox
behavior of porphyrins, two new classes of β-pyrrole mixed substituted free-base …

The synthesis, electrochemistry, spectroscopy, and structural characterization of two high-
valent phenyl σ-bonded cobalt corroles containing a central cobalt ion in formal+ IV and+ V …