Applications of palladium-catalyzed C–N cross-coupling reactions
Pd-catalyzed cross-coupling reactions that form C–N bonds have become useful methods to
synthesize anilines and aniline derivatives, an important class of compounds throughout …
synthesize anilines and aniline derivatives, an important class of compounds throughout …
Guanidines: from classical approaches to efficient catalytic syntheses
From organosuperbases capable of base-catalyzing organic reactions, through versatile
'ligand-sets' for use in coordination chemistry, to fundamental entities in medicinal chemistry …
'ligand-sets' for use in coordination chemistry, to fundamental entities in medicinal chemistry …
Additive-free synthesis of S-substituted isothioureas via visible-light-induced four-component reaction of α-diazoesters, aryl isothiocyanates, amines and cyclic ethers
Y Lv, H Ding, J You, W Wei, D Yi - Chinese Chemical Letters, 2024 - Elsevier
An additive-free and environmentally friendly strategy has been realized for the construction
of S-substituted isothioureas through visible-light-induced multicomponent reaction starting …
of S-substituted isothioureas through visible-light-induced multicomponent reaction starting …
Catalytic methods for aromatic C–H amination: an ideal strategy for nitrogen-based functional molecules
Transformations of aromatic compounds into the corresponding amines, amides, and imides
through carbon–hydrogen (C–H) bond functionalization represent one of the most step-and …
through carbon–hydrogen (C–H) bond functionalization represent one of the most step-and …
Enantioselective Synthesis of Atropisomeric Biaryls by Pd‐Catalyzed Asymmetric Buchwald–Hartwig Amination
P Zhang, XM Wang, Q Xu, CQ Guo, P Wang… - Angewandte …, 2021 - Wiley Online Library
N− C Biaryl atropisomers are prevalent in natural products and bioactive drug molecules.
However, the enantioselective synthesis of such molecules has not developed significantly …
However, the enantioselective synthesis of such molecules has not developed significantly …
7-Azaindole N-Oxide (7-AINO) Mediated Cu-Catalyzed N-Arylation: Mechanistic Investigation into the Role of Fluoride Ions
A Cu (II) fluoride-catalyzed N-arylation of 7-azaindole N-oxides (7-AINO) has been
developed using boronic acid under base-free conditions. During the process, a …
developed using boronic acid under base-free conditions. During the process, a …
[PDF][PDF] Sustainable synthesis of diverse privileged heterocycles by palladium‐catalyzed aerobic oxidative isocyanide insertion
Heterocycles containing a guanidine moiety are of great importance in medicinal chemistry
(Scheme 1).[1] As a result, several methods for the synthesis of these “privileged scaffolds” …
(Scheme 1).[1] As a result, several methods for the synthesis of these “privileged scaffolds” …
Metal-catalyzed reactions of organic nitriles and boronic acids to access diverse functionality
The nitrile or cyano (–CN) group is one of the most appreciated and effective functional
groups in organic synthesis, having a polar unsaturated C–N triple bond. Despite sufficient …
groups in organic synthesis, having a polar unsaturated C–N triple bond. Despite sufficient …
[PDF][PDF] Copper-mediated synthesis of 1, 2, 3-triazoles from N-tosylhydrazones and anilines
Z Chen, Q Yan, Z Liu, Y Xu, Y Zhang - Angew. Chem., Int. Ed, 2013 - researchgate.net
1, 2, 3-Triazoles have found wide application in chemistry, biology, and materials science.[1]
Therefore, general methods for their synthesis are of considerable importance.[2] …
Therefore, general methods for their synthesis are of considerable importance.[2] …
Copper-catalyzed oxidative diamination of terminal alkynes by amidines: synthesis of 1, 2, 4-trisubstituted imidazoles
An efficient copper-catalyzed synthesis of 1, 2, 4-trisubstituted imidazoles using amidines
and terminal alkynes has been developed. Overall, the oxidative process, which involves …
and terminal alkynes has been developed. Overall, the oxidative process, which involves …