Molecular photoswitches in aqueous environments

J Volarić, W Szymanski, NA Simeth… - Chemical Society …, 2021 - pubs.rsc.org
Molecular photoswitches enable dynamic control of processes with high spatiotemporal
precision, using light as external stimulus, and hence are ideal tools for different research …

The many flavours of mechanochemistry and its plausible conceptual underpinnings

RT O'Neill, R Boulatov - Nature Reviews Chemistry, 2021 - nature.com
Mechanochemistry describes diverse phenomena in which mechanical load affects
chemical reactivity. The fuzziness of this definition means that it includes processes as …

Experimental quantitation of molecular conditions responsible for flow-induced polymer mechanochemistry

RT O'Neill, R Boulatov - Nature Chemistry, 2023 - nature.com
Fragmentation of macromolecular solutes in rapid flows is of considerable fundamental and
practical importance. The sequence of molecular events preceding chain fracture is poorly …

Stiff‐stilbene photoswitches: from fundamental studies to emergent applications

D Villarón, SJ Wezenberg - Angewandte Chemie, 2020 - Wiley Online Library
Stiff‐stilbene, a sterically restricted fused ring analogue of stilbene, has been regularly used
as a model compound in theoretical studies of stilbene photoisomerization. Lately, owing to …

Mechanochemical activation of covalent bonds in polymers with full and repeatable macroscopic shape recovery

GR Gossweiler, GB Hewage, G Soriano… - ACS Macro …, 2014 - ACS Publications
Covalent mechanochemistry within bulk polymers typically occurs with irreversible
deformation of the parent material. Here we show that embedding mechanophores into an …

Tuning hardness in calcite by incorporation of amino acids

YY Kim, JD Carloni, B Demarchi, D Sparks, DG Reid… - Nature materials, 2016 - nature.com
Structural biominerals are inorganic/organic composites that exhibit remarkable mechanical
properties. However, the structure–property relationships of even the simplest building unit …

Polymer mechanochemistry: manufacturing is now a force to be reckoned with

N Willis-Fox, E Rognin, TA Aljohani, R Daly - Chem, 2018 - cell.com
Polymer mechanochemistry is an exciting, rapidly develo** field; however, it lacks
detailed studies on the link between lab-scale mechanical activation and how the chemistry …

“Stretching” the energy landscape of oxides—Effects on electrocatalysis and diffusion

B Yildiz - Mrs Bulletin, 2014 - cambridge.org
Elastic strain engineering offers a new route to enable high-performance catalysts,
electrochemical energy conversion devices, separation membranes and memristors. By …

Advances in quantum mechanochemistry: electronic structure methods and force analysis

T Stauch, A Dreuw - Chemical Reviews, 2016 - ACS Publications
In quantum mechanochemistry, quantum chemical methods are used to describe molecules
under the influence of an external force. The calculation of geometries, energies, transition …

Applications of photoswitches in the storage of solar energy

CL Sun, C Wang, R Boulatov - ChemPhotoChem, 2019 - Wiley Online Library
Photoswitches are organic or organometallic chromophores that undergo a reversible
chemical transformation upon absorption of light. Among the most commonly studied …