Microenvironment engineering of single/dual‐atom catalysts for electrocatalytic application

Y Gao, B Liu, D Wang - Advanced Materials, 2023 - Wiley Online Library
Single/dual‐metal atoms supported on carbon matrix can be modulated by coordination
structure and neighboring active sites. Precisely designing the geometric and electronic …

Metalated covalent organic frameworks: from synthetic strategies to diverse applications

Q Guan, LL Zhou, YB Dong - Chemical Society Reviews, 2022 - pubs.rsc.org
Covalent organic frameworks (COFs) are a class of organic crystalline porous materials
discovered in the early 21st century that have become an attractive class of emerging …

Supramolecular tuning of supported metal phthalocyanine catalysts for hydrogen peroxide electrosynthesis

BH Lee, H Shin, AS Rasouli, H Choubisa, P Ou… - Nature Catalysis, 2023 - nature.com
Two-electron oxygen reduction offers a route to H2O2 that is potentially cost-effective and
less energy-intensive than the industrial anthraquinone process. However, the catalytic …

Co(CN)3 catalysts with well-defined coordination structure for the oxygen reduction reaction

K Sun, J Dong, H Sun, X Wang, J Fang, Z Zhuang… - Nature Catalysis, 2023 - nature.com
Metal-nitrogen-doped carbon (MNC) catalysts are promising platinum group metals
alternatives for fuel cell cathodes; however, their randomly formed, unpredictable …

Enhancing H2O2 Electrosynthesis at Industrial-Relevant Current in Acidic Media on Diatomic Cobalt Sites

H Huang, M Sun, S Li, S Zhang, Y Lee… - Journal of the …, 2024 - ACS Publications
Electrocatalytic synthesis of hydrogen peroxide (H2O2) in acidic media is an efficient and
eco-friendly approach to produce inherently stable H2O2, but limited by the lack of selective …

Edge‐Site Engineering of Defective Fe–N4 Nanozymes with Boosted Catalase‐Like Performance for Retinal Vasculopathies

R Zhang, B Xue, Y Tao, H Zhao, Z Zhang… - Advanced …, 2022 - Wiley Online Library
Extensive efforts are devoted to refining metal sites for optimizing the catalytic performance
of single‐atom nanozymes (SANzymes), while the contribution of the defect environment of …

Confining and Highly Dispersing Single Polyoxometalate Clusters in Covalent Organic Frameworks by Covalent Linkages for CO2 Photoreduction

M Lu, M Zhang, J Liu, TY Yu, JN Chang… - Journal of the …, 2022 - ACS Publications
Single clusters have attracted extensive research interest in the field of catalysis. However,
achieving a highly uniform dispersion of a single-cluster catalyst is challenging. In this work …

N B OH Site‐Activated Graphene Quantum Dots for Boosting Electrochemical Hydrogen Peroxide Production

M Fan, Z Wang, K Sun, A Wang, Y Zhao… - Advanced …, 2023 - Wiley Online Library
Carbon materials are considered promising 2/4 e− oxygen reduction reaction (ORR)
electrocatalysts for synthesizing H2O2/H2O via regulating heteroatom dopants and …

Efficient Photosynthesis of Hydrogen Peroxide by Cyano‐Containing Covalent Organic Frameworks from Water, Air and Sunlight

Y Hou, P Zhou, F Liu, Y Lu, H Tan, Z Li… - Angewandte …, 2024 - Wiley Online Library
The insufficient exciton (e−‐h+ pair) separation/transfer and sluggish two‐electron water
oxidation are two main factors limiting the H2O2 photosynthetic efficiency of covalent …

Tailoring acidic oxygen reduction selectivity on single-atom catalysts via modification of first and second coordination spheres

C Tang, L Chen, H Li, L Li, Y Jiao… - Journal of the …, 2021 - ACS Publications
Product selectivity in multielectron electrocatalytic reactions is crucial to energy conversion
efficiency and chemical production. However, a present practical drawback is the limited …