Atom transfer radical polymerization
Atom transfer radical polymerization (ATRP) is a synthetic method that harnesses radical
polymerization to yield well-defined polymers of controlled architecture from a wide range of …
polymerization to yield well-defined polymers of controlled architecture from a wide range of …
Alternating styrene–propylene and styrene–ethylene copolymers prepared by photocatalytic decarboxylation
Synthesis of olefin–styrene copolymers with defined architecture is challenging due to the
limitations associated with the inherent reactivity ratios for these monomers in radical or …
limitations associated with the inherent reactivity ratios for these monomers in radical or …
Alternating Methyl Methacrylate/n-Butyl Acrylate Copolymer Prepared by Atom Transfer Radical Polymerization
Poly (methyl methacrylate/n-butyl acrylate)[P (MMA/BA)] copolymer with an alternating
structure was synthesized via an activator regenerated by electron transfer (ARGET) atom …
structure was synthesized via an activator regenerated by electron transfer (ARGET) atom …
Xanthates in RAFT polymerization
This bibliographic review of xanthate‐mediated RAFT polymerization underlines some
fundamental aspects of this class of singular transfer agents and exhaustively covers the …
fundamental aspects of this class of singular transfer agents and exhaustively covers the …
Effect of hydrophilic monomer distribution on self‐assembly of a pH‐responsive copolymer: spheres, worms and vesicles from a single copolymer composition
A series of copolymers containing 50 mol% acrylic acid (AA) and 50 mol% butyl acrylate
(BA) but with differing composition profiles ranging from an AA‐BA diblock copolymer to a …
(BA) but with differing composition profiles ranging from an AA‐BA diblock copolymer to a …
Influence of Chain Length of Gradient and Block Copoly (2‐oxazoline) s on Self‐Assembly and Drug Encapsulation
O Sedlacek, V Bardoula, E Vuorimaa‐Laukkanen… - Small, 2022 - Wiley Online Library
Amphiphilic gradient copolymers represent a promising alternative to extensively used block
copolymers due to their facile one‐step synthesis by statistical copolymerization of …
copolymers due to their facile one‐step synthesis by statistical copolymerization of …
Spontaneous Gradients by ATRP and RAFT: Interchangeable Polymerization Methods?
KGE Bradford, RD Gilbert, MASN Weerasinghe… - …, 2023 - ACS Publications
The spontaneous gradient polymerization was investigated by ATRP and RAFT. The model
monomers for both systems were methyl methacrylate (MMA) and ethyl acrylate (EA) …
monomers for both systems were methyl methacrylate (MMA) and ethyl acrylate (EA) …
Self-Assembly, Drug Encapsulation, and Cellular Uptake of Block and Gradient Copolymers of 2-Methyl-2-oxazine and 2-n-Propyl/butyl-2-oxazoline
D Babuka, K Kolouchova, L Loukotova… - …, 2021 - ACS Publications
Self-assembled amphiphilic polymers have been extensively studied for various biomedical
applications, as they show advantageous properties for diagnosis and therapy. In this work …
applications, as they show advantageous properties for diagnosis and therapy. In this work …
Unexpected reactivity switch in the statistical copolymerization of 2-oxazolines and 2-oxazines enabling the one-step synthesis of amphiphilic gradient copolymers
Poly (2-oxazoline) s and, more recently, also poly (2-oxazine) s represent an emerging class
of polymers with a broad range of applications. Surprisingly, to date, the statistical …
of polymers with a broad range of applications. Surprisingly, to date, the statistical …
The poly (propylene oxide-co-ethylene oxide) gradient is controlled by the polymerization method: determination of reactivity ratios by direct comparison of different …
J Blankenburg, E Kersten, K Maciol, M Wagner… - Polymer …, 2019 - pubs.rsc.org
An investigation of the highly relevant copolymerization of ethylene oxide (EO) and
propylene oxide (PO) by in situ1H NMR spectroscopy shows striking differences in the …
propylene oxide (PO) by in situ1H NMR spectroscopy shows striking differences in the …