Probing the surfaces of heterogeneous catalysts by in situ IR spectroscopy

C Lamberti, A Zecchina, E Groppo… - Chemical Society …, 2010 - pubs.rsc.org
This critical review describes the reactivity of heterogeneous catalysts from the point of view
of four simple, but essential for Chemistry, molecules (namely dihydrogen, carbon …

[PDF][PDF] EXAFS and XANES analysis of oxides at the nanoscale

A Kuzmin, J Chaboy - IUCrJ, 2014 - journals.iucr.org
Worldwide research activity at the nanoscale is triggering the appearance of new, and
frequently surprising, materials properties in which the increasing importance of surface and …

Insights into Adsorption of NH3 on HKUST-1 Metal–Organic Framework: A Multitechnique Approach

E Borfecchia, S Maurelli, D Gianolio… - The Journal of …, 2012 - ACS Publications
We report a careful characterization of the interaction of NH3 with the Cu (II) sites of the
[Cu2C4O8] paddle-wheel cornerstone of the HKUST-1 metallorganic framework, also known …

Local structure of CPO-27-Ni metallorganic framework upon dehydration and coordination of NO

F Bonino, S Chavan, JG Vitillo, E Groppo… - Chemistry of …, 2008 - ACS Publications
Coordination polymer Ni2 (dhtp)(H2O) 2· 8H2O is a 3D network that maintains crystallinity
and porosity after solvent removal. A mild thermal treatment in high vacuo at 393 K removes …

Carbon monoxide MgO from dispersed solids to single crystals: a review and new advances

G Spoto, EN Gribov, G Ricchiardi, A Damin… - Progress in surface …, 2004 - Elsevier
In this review we describe 30 years of research on the surface properties of magnesium
oxide, considered as the model prototype oxide of cubic structure. The surface properties of …

Low-dimensional systems investigated by x-ray absorption spectroscopy: a selection of 2D, 1D and 0D cases

L Mino, G Agostini, E Borfecchia… - Journal of Physics D …, 2013 - iopscience.iop.org
Over the last three decades low-dimensional systems have attracted increasing interest both
from the fundamental and technological points of view due to their unique physical and …

Core–shell structure of palladium hydride nanoparticles revealed by combined X-ray absorption spectroscopy and X-ray diffraction

AL Bugaev, AA Guda, KA Lomachenko… - The Journal of …, 2017 - ACS Publications
We report an in situ, temperature and H2 pressure-dependent, characterization of (2.6±0.4)
nm palladium nanoparticles supported on active carbon during the process of hydride phase …

Determination of the electronic and structural configuration of coordination compounds by synchrotron-radiation techniques

C Garino, E Borfecchia, R Gobetto… - Coordination Chemistry …, 2014 - Elsevier
In this review we provide an overview of the potential of synchrotron radiation techniques to
understand the structural and electronic properties of coordination compounds. Besides the …

CO adsorption on CPO-27-Ni coordination polymer: spectroscopic features and interaction energy

S Chavan, JG Vitillo, E Groppo, F Bonino… - The Journal of …, 2009 - ACS Publications
The microporous metal− organic framework Ni2 (dhtp)(H4dhtp= 2, 5-dihydroxyterephtalic
acid) is a 3D network that maintains crystallinity and porosity after solvent removal. A mild …

The insights from X-ray absorption spectroscopy into the local atomic structure and chemical bonding of metal–organic frameworks

MA Soldatov, A Martini, AL Bugaev, I Pankin… - Polyhedron, 2018 - Elsevier
After a short introduction highlighting the potentialities of metal–organic frameworks (MOFs)
and the power of X-ray absorption spectroscopies (XAS), a list of selected examples follows …