Kinetics controlled microstructure and composition in coordinative chain transfer copolymerization of ethylene–propylene

A Dashti, M Ahmadi, V Haddadi-Asl, S Ahmadjo… - Journal of Molecular …, 2023 - Elsevier
The wide applications of ethylene–propylene copolymers, which range from elastomers to
oligomeric lubricants and additives can be expanded upon controlling the microstructure …

Complex interplay of short-and long-chain branching on thermal and rheological properties of ethylene/α-olefin copolymers made by metallocene catalysts with …

M Ahmadi, F Rezaei, SMM Mortazavi, M Entezam… - Polymer, 2017 - Elsevier
Unbridged oscillatory metallocenes are prone to produce heterogeneous chain
microstructure, for instance, giving rise to elastomeric polypropylene. Here, we use the bis (2 …

Copolymerization of ethylene/α‐olefins using bis (2‐phenylindenyl) zirconium dichloride metallocene catalyst: structural study of comonomer distribution

SMM Mortazavi, H Arabi, G Zohuri… - Polymer …, 2010 - Wiley Online Library
Catalysts have a major role in the polymerization of olefins and exert their influence in three
ways:(1) polymerization behaviour, including polymerization activity and kinetics;(2) polymer …

Interplay of reversible chain transfer and comonomer incorporation reactions in coordination copolymerization of ethylene/1–hexene

A Ebrahimi, S Ahmadjo, M Mohammadi… - Polyolefins …, 2019 - poj.ippi.ac.ir
Coordinative chain transfer polymerization (CCTP) has opened a new path for the
development of novel products like olefin block copolymers and chain-end functional …

Estimation of Polymerization Conditions Needed to Make Ethylene/1‐olefin Copolymers with Specific Microstructures Using Artificial Neural Networks

T Charoenpanich, S Anantawaraskul… - Macromolecular …, 2016 - Wiley Online Library
Two artificial neural network models (forward and inverse) are developed to describe
ethylene/1‐olefin copolymerization with a catalyst having two site types using training and …

Structural analysis of linear/branched ethylene block copolymers

M Karimi, SMM Mortazavi, S Ahmadjo… - Polymers for …, 2018 - Wiley Online Library
Chain shuttling polymerization has provided new pathway for introduction of different
architectures in a single chain. Unlike the commercially available ethylene/1‐octene block …

Comparative study of copolymerization and terpolymerization of ethylene/propylene/diene monomers using metallocene catalyst

M Mortazavi, H Arabi, S Ahmadjo… - Journal of Applied …, 2011 - Wiley Online Library
Abstract (Ind) 2ZrCl2 catalyst was synthesized and used for copolymerization of ethylene
and propylene (EPR) and terpolymerization of ethylene propylene and 5‐ethyldiene‐2 …

Investigation into the effect of branch length of polyolefin and its statistical distribution on the flow improving performance

SMM Mortazavi, S Ahmadjo, M Omidvar… - Journal of Polymer …, 2021 - Springer
Ultra high molecular weight polyolefins as the main category of drag reducing agents play
the main role in energy transportation. The present study seek to thoroughly investigate, the …

Terpolymerization of Ethylene/Propylene/Diene Monomers Using (2‐PhInd)2ZrCl2 Metallocene Catalysts

S Ahmadjo, H Arabi, M Nekoomanesh… - Macromolecular …, 2010 - Wiley Online Library
PhInd) 2ZrCl2 was synthesized and used for the first time in the terpolymerization of
ethylene, propylene and 5‐ethylidiene‐2‐norbornene (ENB). It showed appropriate activity …

Correlation of polymerization conditions with drag reduction efficiency of poly (1-hexene) in oil pipelines

SMM Mortazavi - Iranian Polymer Journal, 2016 - Springer
High molecular weight with long linear side branches are frequently used in oil pipelines as
one of the main classes of drag reducer agents (DRAs). We studied the effects of …