Transition metal catalysis has dramatically changed the face of modern organic chemistry by
introducing a range of novel synthetic methods. A number of outstanding catalytic systems …

The hydrothiolation of unsaturated carbon–carbon bonds is a practical and atom‐
economical approach for the incorporation of sulfur into organic frameworks. In recent years …

Cyanoformates and cyanoformamides are found to add across alkynes by nickel/Lewis acid
(LA) cooperative catalysis to give β-cyano-substituted acrylates and acrylamides …

A Rh (I)-catalyzed method for the efficient functionalization of arenes is reported. Aryl methyl
sulfides are combined with terminal alkynes to deliver products of carbothiolation. The …

The transition metal mediated synthesis of carbon–sulfur (C–S) bonds is possible with a
variety of simple and tailored metal complexes. This chapter serves to illustrate …

The present study reports the evidence for the multiple carbon–carbon bond insertion into
the metal–heteroatom bond via a five‐coordinate metal complex. Detailed analysis of the …

Chlorothiolation of terminal alkynes with sulfenyl chlorides yields anti‐adducts without
transition‐metal catalysts. In sharp contrast, transition‐metal‐catalyzed chlorothiolation has …

This chapter deals with the transition-metal-catalyzed hydrothiolation and hydroselenation of
alkynes and allenes and related unsaturated compounds with thiols and selenols. In these …

This mini-review focuses on addition reactions, as atomeconomic reactions, employed for
the preparation of organosulfur and organophosphorus compounds. For synthesis of …

Nickel-catalysed synthesis of tetrasubstituted vinyl sulfides from thiocarbamates and internal
alkynes - Chemical Communications (RSC Publishing) DOI:10.1039/C4CC09123J Royal Society …