Aqueous iron (IV)–oxo complex: an emerging powerful reactive oxidant formed by iron (II)-based advanced oxidation processes for oxidative water treatment
Z Wang, W Qiu, S Pang, Q Guo, C Guan… - … Science & Technology, 2022 - ACS Publications
High-valent iron (IV)–oxo complexes are of great significance as reactive intermediates
implicated in diverse chemical and biological systems. The aqueous iron (IV)–oxo complex …
implicated in diverse chemical and biological systems. The aqueous iron (IV)–oxo complex …
Dioxygen activation at mononuclear nonheme iron active sites: enzymes, models, and intermediates
M Costas, MP Mehn, MP Jensen, L Que - Chemical reviews, 2004 - ACS Publications
There have been significant advances in our understanding of mononuclear nonheme iron
oxygenases since our 1996 Chemical Reviews article, 1 promoted in large part by the many …
oxygenases since our 1996 Chemical Reviews article, 1 promoted in large part by the many …
α-Fe2O3 as a versatile and efficient oxygen atom transfer catalyst in combination with H2O as the oxygen source
Abstract Haematite (α-Fe2O3) has been extensively investigated as a photoanode in
photoelectrochemical water oxidation, but the product O2 has a low economic value. Here …
photoelectrochemical water oxidation, but the product O2 has a low economic value. Here …
Prediction of molecular properties and molecular spectroscopy with density functional theory: From fundamental theory to exchange-coupling
F Neese - Coordination Chemistry Reviews, 2009 - Elsevier
This review provides a detailed account of density functional theory (DFT) and its application
to the calculation of molecular properties of inorganic compounds. After introducing some …
to the calculation of molecular properties of inorganic compounds. After introducing some …
High-valent iron (IV)–oxo complexes of heme and non-heme ligands in oxygenation reactions
W Nam - Accounts of chemical research, 2007 - ACS Publications
High-valent iron (IV)–oxo species have been implicated as the key reactive intermediates in
the catalytic cycles of dioxygen activation by heme and non-heme iron enzymes. Our …
the catalytic cycles of dioxygen activation by heme and non-heme iron enzymes. Our …
Fe (II)/α-ketoglutarate-dependent hydroxylases and related enzymes
RP Hausinger - Critical reviews in biochemistry and molecular …, 2004 - Taylor & Francis
Fe (II)/α-ketoglutarate (αKG)-dependent hydroxylases catalyze an amazing diversity of
reactions that result in protein side-chain modifications, repair of alkylated DNA/RNA …
reactions that result in protein side-chain modifications, repair of alkylated DNA/RNA …
Efficient water oxidation catalysts based on readily available iron coordination complexes
Water oxidation catalysis constitutes the bottleneck for the development of energy-
conversion schemes based on sunlight. To date, state-of-the-art homogeneous water …
conversion schemes based on sunlight. To date, state-of-the-art homogeneous water …
Non-heme Fe (IV)–oxo intermediates
High-valent non-heme iron–oxo intermediates have been proposed for decades as the key
intermediates in numerous biological oxidation reactions. In the past three years, the first …
intermediates in numerous biological oxidation reactions. In the past three years, the first …
Recognition of surface oxygen intermediates on NiFe oxyhydroxide oxygen-evolving catalysts by homogeneous oxidation reactivity
NiFe oxyhydroxide is one of the most promising oxygen evolution reaction (OER) catalysts
for renewable hydrogen production, and deciphering the identity and reactivity of the oxygen …
for renewable hydrogen production, and deciphering the identity and reactivity of the oxygen …
Reactive high-spin iron (IV)-oxo sites through dioxygen activation in a metal–organic framework
In nature, nonheme iron enzymes use dioxygen to generate high-spin iron (IV)= O species
for a variety of oxygenation reactions. Although synthetic chemists have long sought to …
for a variety of oxygenation reactions. Although synthetic chemists have long sought to …